The kinetics and mechanism of ligand substitution reactions of [Pt(SMC)Cl(2)] (SMC = S-methyl-l-cysteine) with biologically relevant ligands were studied as a function of chloride and nucleophile concentrations at pH 2.5 and 7.2. It was observed that the slope and intercept obtained from the linear dependence of the observed rate constant on the nucleophile concentration strongly depend on the ...

the vo(iv) complexes of tridentate ono schiff base ligands derived from 2- aminobenzoicacid and salicylaldehyde derivatives were synthesized and characterized by ir, uv–vis and elemental analysis. electrochemical properties of the vanadyl complexes were investigated by cyclic voltammetry. a good linear correlation was observed between the oxidation potentials and the electron-withdrawing charac...

The fabrication and electrochemical evaluation of two PVC membrane-based Ion-Selective electrodes responsive for ramipril drug have been proposed. The sensitive membranes were prepared using ramipril-phosphomolibdate and ramipril-tetraphenylborate ion-pair complexes as electroactive sensing materials in plasticized PVC support. The electrodes based on these materials provide near-Nernestian res...

The new [Co(Salen)(PBu3)2]ClO4, [Co(Salen)(PBu3)2]BF4, [Co(Salpn)(PBu3)2]ClO4 and [Co(Salen)(PMe2Ph)2]ClO4 ( where salen = bis(salisylaldehyde)ethylenediimine)) complexes were synthesiszed and chracterized by IR, UV-Vis, 1H NMR spectroscopy and elemental analysis. The IR and 1H NMR spectra cofirmed that the synthesised complexes contain Schiff base ligand, phosphane and conter ion and the eleme...

The excited-state proton transfer and subsequent intramolecular ion pair formation of a cupreidine-derived Cinchona organocatalyst (BnCPD) were studied in THF-water mixtures using picosecond time-resolved fluorescence together with global analysis. Full spectral and kinetic characterization of all the fluorescent species allowed us to monitor the 3-step process for the ion pair dissociation. In...

the computer simulation program of a practical scale reverse electrodialysis process has been developed based on the program for saline water electrodialysis. the program is applied to compute the performance of an industrial-scale reverse electrodialysis stack (effective membrane area s = 1 m × 1 m = 1 m2, cell pair number n = 300 pairs). the stack operatingconditions are optimized. seawater a...

NMR experiments on sodium biphenyl (NaBp), potassium biphenyl (KBp) and ribidium biphenyl (RbBp), dissolved in various solvents are summarized with emphasis on the structural information which can be obtained from such experiments. The crystal structures of NaBp.2Tg (Tg = triglyme), KBp.2Ttg and RbBp.2Ttg (Ttg tetraglyme) are discussed, in relation to the NMR results obtained for these systems ...

The present work reported density, viscosity, speed of sound, electrical conductivity and refractive index data of L-alanine in the aqueous solutions of 1-hexyl-3-methylimidazolium ibuprofenate at T= 298.15 K. Using the measured data, partial molar volume of transfer ( ), partial molar isentropic compressibility of transfer ( ), viscosity B-coefficient of transfer (∆traB), ion association const...

Abstract The formation of dust ion-acoustic shocks (DIASs) in a four-component quantum plasma whose constituents are electrons, both positive and negative ions and immobile charged dust grains, is studied. The effects of both the dissipation due to kinematic viscosity and the dispersion caused by the charge separation as well as the quantum tunneling due to the Bohm potential are taken into acc...

the reaction of an equivalent of 2- mercaptoethyl ammonium chloride with an equivalent of 2,6-diformyl -4- methyl phenol produced monoamine which was reacted with half equivalent of 1,2-diamine ethane to produce ethylene-bis-6-(2-mercapto-ethyl-imine)-methyl -4- methyl phenol [h4l]. the ligand was reacted with metal ions[cr(iii), mn(ii), fe(ii), co(ii), ni(ii), cu(ii), zn(ii), cd(ii), and hg(ii...