The microsolvation of LiBO2 in water was investigated by conducting anion photoelectron spectroscopy and ab initio studies on the LiBO2(H2O)n(-) (n = 0-5) clusters. By comparing calculations with experiments, the structures of these clusters and their corresponding neutrals were assigned, and their structural evolutions were revealed. During the anionic structural evolution with n increasing to...

The stability of the mercury ion mediated dU-HgII-dU pair depends on substituents introduced at the 5-position of the pyrimidine moiety. To this end, a series of oligonucleotides were synthesized with dU modification in central position. Common and new phosphoramidites were utilized. Hybridization experiments provided 12-mer duplexes with non-canonical "dU-dU" pairs. In most cases Hg2+ stabiliz...

The objective of this study was to examine whether ion pair complexation with endogenous bile salts in hepatocytes contributes to the preferential biliary excretion of organic cations (OCs). Tributylmethylammonium (TBuMA; mol wt 200) and triethylmethylammonium (TEMA; mol wt 116) were selected as model OCs that exhibit significant and negligible biliary excretion, respectively, in rats. The appa...

In central collisions at relativistic heavy ion colliders like the Relativistic Heavy Ion Collider RHIC/Brookhaven and the Large Hadron Collider LHC (in its heavy ion mode) at CERN/Geneva, one aims at detecting a new form of hadronic matter — the Quark Gluon Plasma. We discuss here a complementary aspect of these collisions, the very peripheral ones. Due to coherence, there are strong electroma...

Three new, simple, rapid and sensitive spectrophotometric methods have been developed for the assay of mebendazole (MBD) in bulk drug, tablets and suspension. First method (method A) is based on the formation of a colored ion-pair complex (1:1 drug/dye) of MBD with bromocresol green (BCG) at pH 1.99 ± 0.01 and extraction of complex into chloroform followed by measurement of yellow ion-pair comp...