We investigate nonequilibrium fluctuations of a solid surface governed by the stochastic Mullins-Herring equation with conserved noise. This equation describes surface diffusion of adatoms accompanied by their exchange between the surface and the bulk of the solid, when desorption of adatoms is negligible. Previous works dealt with dynamic scaling behavior of the fluctuating interface. Here we ...

The solid particles are adsorbed at interfaces and form self-assembled structures when the particles have suitable wettability to both liquids. Here, we show theoretically how the microstructure on the particle surface affects their adsorption properties. The physical properties of the interface adsorbing a particle will be described by taking into account the surface roughness due to the micro...

While the structure and dynamics of boundary layers on rigid no-slip walls in rotation dominated enclosed flows are still an area of active research, the interactions between rotating or swirling flows with a free surface have received comparatively less attention. For the most part, investigations in this area have been focused on clean free surfaces, which may be treated as stress-free. Howev...

Results of flow visualization experiments are presented to clearly identify the trigger mechanism for critical heat flux (CHF) in flow boiling. It is shown that discrete bubbles which form following the onset of nucleation coalesce into a wavy vapor layer at fluxes well below CHF. Depressions in the layer interface were observed to touch the heater surface periodically, painting a thin liquid s...

We investigate surface modes in plasmonic Bragg fibers composed of nanostructured coaxial cylindrical metal-dielectric multilayers. We demonstrate that the existence of surface modes is determined by the sign of the spatially averaged permittivity of the plasmonic Bragg fiber, ε¯. Specifically, localized surface modes occur at the interface between the cylindrical core with ε¯<0 and the outermo...

With molecular simulation for water and a tunable hydrophobic substrate, we apply the instantaneous interface construction [A. P. Willard and D. Chandler, "Instantaneous liquid interfaces," J. Phys. Chem. B 114, 1954-1958 (2010)] to examine the similarity between a water-vapor interface and a water-hydrophobic surface interface. We show that attractive interactions between a hydrophobic surface...

The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. With molecular simulation for water and a tunable hydrophobic substrate, we apply the instantaneous interface construction [A.] to examine the similarity between a water-vapor interface and a water-hydrophobic surface interface. The intrinsic interface refers to molecular struc...

Thermodynamically consistent phase fi eld theory for various phase transformations (including multivariant martensitic transformations, melting, and twinning), which includes interface stresses, is developed [1–5]. Free energy includes several local polynomials in terms of the order parameters describing phase transformations and depends on their gradient in the current confi guration. Theory i...

The surfaces of aqueous solutions are traditionally viewed as devoid of inorganic ions. Molecular simulations and surface-selective spectroscopic techniques show, however, that large polarizable anions and hydronium cations can be found (and even enhanced) at the surface and are involved in chemistry at the air/water interface. Here, we review recent studies of ions at the air/water interface a...