Introduction Poly(urethane urea) multiblock copolymers [PUU] are used in variety of biomedical applications, including as blood-contacting components in ventricular assist systems. One of the drawbacks of these materials (particularly when used in completely implantable devices) is their relatively high permeability to air and moisture. Conventional biomedical PUU elastomers are generally compo...

Assembling nanoparticles into one-dimensional (1D) nanostructures with precisely controlled size and shape renders the exploration of new properties and construction of 1D miniaturized devices possible. The physical properties of such nanostructures depend heavily on the size, chemical composition, and surface chemistry of nanoparticle constituents, as well as the close proximity of adjacent na...

A novel interfacial hybrid epoxidation catalyst was designed with a new immobilization method for homogeneous catalysts by coating an inorganic support with an organic polymer film containing active sites. The titanium silsesquioxane (TiPOSS) complex, which contains a single-site titanium active center, was immobilized successfully by in-situ copolymerization on a mesoporous SBA-15-supported po...

In this work, the thermal stabilities of a series of polyethylene glycols (PEG 4000, 6000 and 10000) were investigated after compositing with different kinds of inorganic salts, such as ammonium molybdate tetrahydrate (AMT), NH4VO3, (NH4)2SO4, NH4NO3, Na2SO4, Na2MoO4. It was first observed that all the ammonium salts exerted leveling effects for the thermal stabilities of the PEGs. In other wor...

Many research studies have been conducted on the use of conjugated polymers in the construction of chemical sensors including potentiometric, conductometric and amperometric sensors or biosensors over the last decade. The induction of conductivity on conjugated polymers by treating them with suitable oxidizing agents won Heeger, MacDiarmid and Shirakawa the 2000 Nobel Prize in Chemistry. Common...

The isothermal enthalpy changes with time of a dental composite were examined by microcalorimetry to isolate the effects of different filler concentrations and curing times on chemical aging of these composites. Urethane dimethacrylate (UDMA) monomer, zirconia-silica (ZS) powder, and 3-methacryloxypropyltrimethoxysilane (MAPM) were used as organic and inorganic matrices, and a coupling agent, r...

This study focuses on the preparation of Ni-plated polystyrene (PS) microspheres (diameter 3.7–4.5 μm). These Ni-plated PS microspheres have core–shell structures that were designed and prepared using an organic polymer core (PS with 3-(trimethoxysilyl) propyl methacrylate (TSPM)) and an inorganic metal (Ni) plated shell. The polymer microspheres were synthesized by dispersion copolymerization,...

Many studies are currently underway on the quest to make synthetic bone-like materials with composites of polymeric materials and hydroxyapatite (HA). In the present work, we use wetting experiments and surface tension measurements to determine the work of adhesion between biodegradable polymers and HA, with specific reference to the role of humid environments. All the polymers are found to exh...

Nanofiltration with inorganic meso-porous membranes is being considered more and more for water purification applications. For specific applications inorganic membranes may have advantages over organic polymer-based membranes due to their rigid pore structure, and thermochemical stability. However, the permeability and, partly through that, the permselectivity of inorganic membranes need to be ...

23 New electrode materials based on composite inorganic redox material–organic conducting polymer for 24 electroanalysis of dopamine were developed. The composite inorganic–organic coatings based on Prus25 sian blue (PB) and poly(3,4-ethylenedioxythiophene) (PEDOT) have been prepared by electrochemical 26 methods onto gold disk microelectrode arrays. Both insoluble and soluble forms of PB were ...