Five novel dumbbell-shaped polyoxometalate (POM)-based inorganic-organic-inorganic molecular hybrids are investigated both in polar solvents and at interfaces for potential amphiphilic properties, which are compared with those of conventional surfactants. These hybrids with the general formula {P(2)V(3)W(15)}(2)-bis(TRIS)-linker are formed by linking two Wells-Dawson-type clusters, [P(2)V(3)W(1...

The production of 2,4-diacetylphloroglucinol (DAPG) by the biocontrol agent Pseudomonas fluorescens Pf-5 was studied in nutrient-solution based media with varying nitrogen content. No production of DAPG was observed when organic nitrogen was omitted from the media, regardless of the inorganic nitrogen source used. Furthermore, a micromolar concentration range of organic nitrogen was insufficien...

Herein, we report a hybrid polyoxometalate organic-inorganic compound, Na2 [(HGMP)2 Mo5 O15 ]⋅7 H2 O (1; where GMP=guanosine monophosphate), which spontaneously assembles into a structure with dimensions that are strikingly similar to those of the naturally occurring left-handed Z-form of DNA. The helical parameters in the crystal structure of the new compound, such as rise per turn and helical...