Mesoporous silica materials have been utilized for various applications (catalysis, sensing, drug delivery, adsorption and separation) due to their uniform mesoporous features as well as high surface areas. When organic polymer layers are introduced to the mesopore walls, the physicochemical properties as well as surface nature of the silica (e.g. hydrophilicity and surface charge) can be alter...

in recent years many research works have been carried out on anti-corrosive nanocomposites coatings containing mineral reinforcements. the most important criteria in these attempts are polymerization method and the type of matrix and reinforcement of nanocomposites. in this regard, the physical and mechanical properties of the polymers in which a small amount of filler is used can be improved. ...

objectives: the aim of this study was to compare polymerization depth of two bulk-fill and one conventional composite cured for different times. methods: this in vitro experimental study was conducted on 54 composite samples (2×4×10mm) fabricated of tetric n-ceram bulk-fill, x-tra fil bulk-fill, and grandio conventional composite cured for 20, 30, and 40 seconds. the microhardness of samples wa...

The polymerization of octamethylcyclotetrasiloxane (D4) is investigated using several five-, six- and seven-membered N-heterocyclic carbenes (NHCs). The catalysts are delivered in situ from thermally susceptible CO2 adducts. It is demonstrated that the polymerization can be triggered from a latent state by mild heating, using the highly nucleophilic 1,3,4,5-tetramethylimidazol-2-ylidene as orga...

Particles of Cobalt ferrite, CoFe2O4-, were coated with polyaniline (PANI) sulphate and phosphate during in-situ polymerization of aniline in an aqueous solution of sulfuric and phosphoric acid. The PANI-ferrite composites were characterized by Fourier transform infrared (FTIR) spectroscopy. Structures and morphology of products were studied by X-Ray Diffraction (XRD) and Scanning Electron Micr...

By mean of heterophase polymerization on the silica gel surface has been made in situ immobilization poly [8-methacroyloxy-quinoline], received new organic-mineral composite material. I...

A simple polymerization of trichlorophosphoranimine (Cl3 P = N-SiMe3 ) mediated by functionalized triphenylphosphines is presented. In situ initiator formation and the subsequent polymerization progress are investigated by (31) P NMR spectroscopy, demonstrating a living cationic polymerization mechanism. The polymer chain lengths and molecular weights of the resulting substituted poly(organo)ph...

This article reports that the kinetics of surface-initiated atom transfer radical polymerization can be quantified by the quartz crystal microbalance with dissipation (QCM-D) technique. The kinetics of in situ growth of poly(oligoethylene glycol methylmethacrylate) monitored on a gold-coated QCM-D sensor chip revealed that changes in the experimentally observed frequency (DeltaF) and dissipatio...

Photoinitiated thiol–ene polymerization was performed in bulk and miniemulsion. We show that the compartmentalization of reaction inside nanodroplets led to faster kinetics yielded polymers with higher molecular weight.

polythiophenes are of considerable interest as synthetic metals. the optical properties of polythiophenes can be easily affected by alkyl chain or other side groups to the thiophene ring. the effect of polymerization degree on the energy gap was studied in the case of polythiophene as a conjugated polymer at b3lyp/6-31+g(3d,3p) level of theory. up to n = 16 could be confident that this degree o...