A methodology for calcium sulfate (gypsum) scale control in nanofiltration of saline waters is presented. The methodology involves the use of both theoretically and experimentally determined parameters. Pitzer’s thermodynamic equations for electrolytes are used to determine the gypsum scaling potential of the feed water based on its ionic composition, whereas the extent of concentration polariz...

The internal surface area of hexagonal (soluble) primary anhydrite CaSO4 produced by dehydration of gypsum decreases by about 70 % when the anhydrite is successively subjected to rehydration and dehydration at room temperature in humid air and in vacuum respectively. In the rehydration step, the hemihydrate is formed; its dehydration yields secondary anhydrite. Additional hydration-dehydration ...

This paper presents results of investigation of scaling of calcium sulfate (CaSO4) on metallic pipes. In this study, the optimizing variables; namely temperature (50-600C), concentration of Ca2+ (2000-3000 ppm), citric acid concentration (10-20 ppm) were set-up to provide the optimum yield of the mass scales. The mineral scale detected using XRD is mainly gypsum, and the scale has a plate like ...

A mathematical model was developed for combined fouling due to biofilms and mineral precipitates in membrane feed channels with spacers. Finite element simulation of flow and solute transport in two-dimensional geometries was coupled with a particle-based approach for the development of a composite (cells and crystals) foulant layer. Three fouling scenarios were compared: biofouling only, scali...

Constructed wetlands are increasingly used for water pollution treatment but may also be sources of the greenhouse gas CH(4). The effect of addition of two potential inhibitors of methanogenesis - iron ochre and gypsum - on net CH(4) emissions was investigated in a constructed wetland treating farm runoff in Scotland, UK. CH(4) fluxes from three 15-m(2) wetland plots were measured between Janua...

Fly ashes and gypsum are one of the main wastes produced in coal-fired power stations which may be sent to landfills for their disposal. In this work, leaching and speciation of mercury in fly ashes and gypsum from a modern co-combustion power plant equipped with a selective catalytic reduction (SCR) unit in the Netherlands were studied. The mercury leachable contents were checked against diffe...

This article focuses on the hydration, and associated microstructure development, of b-hemihydrate to dihydrate (gypsum). The sound velocity is used to quantify the composition of the fresh slurry as well as the hardening and hardened—porous—material. Furthermore, an overview of available hydration kinetic and volumetric models for gypsum is addressed. The presented models predict the sound vel...

We recently showed that the production of elemental sulphur and calcium carbonate (CaCO3) from gypsum waste by thermally reducing the waste into calcium sulphide (CaS) followed by its direct aqueous carbonation yielded low-grade carbonate products (i.e. <90 mass% as CaCO3). In this study, we used the insight gained from our previous work and developed an indirect aqueous CaS carbonation process...

The impacts of temperature on the surface thermal damage of rock salt, gypsum and mudstone from the Yingcheng salt mine, China were investigated by the surface crack growth and propagation tests at different temperatures. We found that: (a) high temperature could strengthen the rock salt molecular thermal motion and weaken the cohesion among the rock salt grains, so that the grain boundaries we...

AIM To compare and evaluate few physical properties of epoxy resin, resin-modified gypsum and conventional type-IV gypsum die material. MATERIALS AND METHODS In the present study, dimensional accuracy, surface detail reproduction and transverse strength of three die materials like epoxy resin (Diemet-E), resin-modified gypsum (Synarock) and conventional type-IV gypsum (Ultrarock) are analyzed...