In this study, a novel acidic magnetic dicationic ionic liquid was prepared in three steps to serve as a green  catalyst  in  organic  synthesis.  The  newly  synthesized  catalyst  was  characterized UV- VIS,  and  VSM  analysis.  Additionally,  the  decomposition  steps  acatalyst  were investigated by thermal  analysis  techniques  (TGA/DSC).  The  synthesized  acidic magnetic dication...

A hydrophobic-bentonite catalyst (cetyltrimethyl ammonium bromide-bentonite) has been used as a very mild, neutral, eco-friendly, reusable, non-toxic, low-cost and easily available catalyst. It was prepared by replacing the exchangeable Na+ cations of a homoionic Na–bentonite with cetyltrimethyl ammonium bromide (CTMAB) cations. The catalyst was characterized by XRD, BET and SEM. The...

An environmentally friendly ("green"), H2-generation system was developed that involved hydrolytic oxidation of inexpensive organosilanes as hydrogen storage materials with newly developed heterogeneous gold nanoparticle catalysts. The gold catalyst functioned well at ambient temperature under aerobic conditions, providing efficient production of pure H2. The newly developed size-selective gold...

Epoxides are an important class of industrial chemicals that have been used as chemical intermediates. Catalytic epoxidation of olefins affords an interesting production technology. We found a widely usable green route to the production of epoxides: A silicotungstate compound, [gamma-SiW10O34(H2O)2]4-, is synthesized by protonation of a divacant, lacunary, Keggin-type polyoxometalate of [gamma-...

in this researchsaccharomyces cerevisiae (baker’s yeast) was used as a cheap, readily accessible, selective, efficient, and green bio-catalyst in a chemo selective reduction of carbonyl group to hydroxyl group. in this green procedure three substrates e.g. (3-(3-nitrophenyl)aziridin-2-yl)-1-phenyl-methanone, pyruvate ester, and 2-acetyl-γ-butyrolactone were reduced to their corresponding reduce...

a simple and mild method for tetrahydropyranylation of alcohols is reported at room temperature using a catalytic amount of 3-methylimidazolinium hydrogensulfate([hmim]hso4) as a green, efficient and reusable catalyst. using solvent-free conditions, non-toxic and inexpensive materials, modest and clean work-up, short reaction times and high yields of the products are the advantages of this method.

a novel and safe method for nitration of phenols, anilines and other aromatic compounds has beenfound to be feasible with alumina sulfuric acid (asa) as catalyst and mg (no3)2.6h2o as nitrating agent inneat water as solvent. the use of water makes this method compatible with the green chemistry approach

β-cyclodextrin sulfuric acid as a green lewis acid catalyst has been applied for the preparation of bis(indolyl)methanes, tris(indolyl)methanes and 3,3'-diindolyloxindole derivatives by the condensation of indoles with various carbonyl compounds in aqueous media with high to excellent yields.

a series of 2-amino pyridine-3-carbinitrile derivatives incorporated coumarin moiety has developed via multicomponent condensation of 3-acetyl-2h-chromen-2-one, arylaldehydes, malononitrile and ammonium acetate utilizing brønsted acidic ionic liquid, (4-sulfobutyl)tris(4-sulfophenyl)phosphonium hydrogen sulfate as catalyst under solvent-free conditions. good yields, short reaction times, straig...

decatungstodivanadogermanic acid (h6gew10v2o40.22h2o) was used as a green heterogeneous catalyst for the synthesis of 3,4-dihydropyrimidin-2-(1h)-ones from one-pot three-component cyclocondensation reaction of a β-ketoester, an aldehyde and urea/thiourea under solvent-free conditions is reported. this method provides an efficient and much improved modification of the original biginelli reaction...