The overall performance of a catalyst particle strongly depends on the ability of mass transport through its pore space. Characterizing the three-dimensional structure of the macro- and mesopore space of a catalyst particle and establishing a correlation with transport efficiency is an essential step toward designing highly effective catalyst particles. In this work, a generally applicable work...

A Y zeolite-containing wide-pore composite was synthesized by in situ technique using polyvinyl alcohol and silica sol material. A fluid catalytic cracking (FCC) catalyst for maximizing gasoline yield was successfully developed with the modified composition. The as-made zeolite Y in its sodium form had a relative crystallinity of 52.9 % with a high silica/alumina amount of substance ratio of 5....

The controlling of exhaust gas from gasoline is crucial for atmospheric environment protection. Research Octane Number (RON) loss and restricted sulphur (S) content matter the quality gasoline. To obtain with high quality, paper proposes a novel data-driven optimization model integrating deep neural network (DNN) genetic algorithm (GA) to Fluid Catalytic Cracking (FCC) process then optimize. be...

A mathematical model for commercial naphtha catalytic reformer of Tehran refinery was developed. This model includes three sequencing fixed beds of Pt/Al2O3 catalyst at the steady state condition using detailed kinetic scheme involving 26 pseudo-components connected by a network of 47 reactions, in the range of C6 to C9 hydrocarbons. The reaction network consisted dehy...

The paper considers the possibility of repurposing a plant for production methyl tert-butyl ether (MTBE) esterification light fraction gasoline by catalytic cracking. conversion MTBE installation to process cracking will allow obtaining an additional amount high-octane component automotive

Among the current IPPC installations, steam cracking for olefin production is the single most energy consuming process (ca. 30%) in the chemical industry, accounting for ca. 180 million tons of CO2 worldwide. This paper reviews steam cracking and innovative emerging olefin technologies in terms of energy efficiency. Pyrolysis section alone consumes ca. 65% of the total energy use and ca. 75% of...

Hierarchical MFI zeolite was synthesized following a synthesis route using organic-inorganic hybrid surfactants; the resultant zeolite with mesoporous/microporous hierarchical structure exhibited remarkably high resistance to deactivation in catalytic activity of various reactions such as isomerization of 1,2,4-trimethylbenzene, cumene cracking, and esterification of benzyl alcohol with hexanoi...

Size selective growth of palladium nano-particles 2-7 nm in diameter on the surface of carbon nano-onions (CNOs) (derived from catalytic cracking of methane) in water involves pretreating the CNOs with p-phosphonic acid calix[8]arene then H(2)PdCl(4) followed by dynamic thin film processing under hydrogen in a vortex fluidic device.