Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-diborylation of carbon-carbon multiple bonds with diboron compounds. These diborylated reagents lead to invention of polyborylated reagents and many novel and useful synthetic methods for supreme stereocontrol. This review summarizes preparati...

preparation and uses of quinaldinium dichromate and its polymeric analogue poly (2- vinylquinolinium) dichromate as the new monomeric and polymeric oxochromium-amine complex reagents for oxidizing variousorganic compounds, with emphasis on the latter, are described

A simple method was created and implemented through the technology of ink-jet printing to study the effects of three chemical factors (chemical reagents) to the ninhydrin reaction. The effects of each single reagent and their interactions on the reaction were studied in one experiment. The three reagents all have effects on ninhydrin reaction, and the effects under the different combinations of...

The preparation of polymer-supported allyltin reagents was shown to be possible for both unfunctionalized and functionalized allyl units. These reagents were treated with aldehydes in the presence of cerium(III) or indium(III) salts to afford high yields of homoallylic alcohols, practically uncontaminated with organotin residues (less than 5 ppm). Some mechanism aspects are briefly discussed an...

Herein we disclose an iron-catalyzed cross-coupling reaction of propargyl ethers with Grignard reagents. The was demonstrated to be stereospecific and allows for a facile preparation optically active allenes via efficient chirality transfer. Various tri- tetrasubstituted fluoroalkyl can obtained in good excellent yields. In addition, reagents α-alkynyl oxetanes tetrahydrofurans is disclosed her...

A procedure has been developed for the purification of amine oxidase (E.C. 1.4.3.4) from etiolated pea epicotyls (Pisum sativum cv. Little Marvel). The enzyme is sensitive to copper chelating reagents and carbonyl reagents, but is not inhibited by sulfhydryl reagents. The purified enzyme has a molecular weight of 1.85 x 10(5), as determined by sedimentation equilibrium centrifugation, and has b...