We report the synthesis of a unique cubic metal–organic framework (MOF), Fe-HHTP-MOF, comprising hexahydroxytriphenylene (HHTP) supertetrahedral units and FeIII ions, arranged in diamond topology. The MOF is synthesized under solvothermal conditions, yielding highly crystalline, deep black powder, with crystallites 300–500 nm size tetrahedral morphology. Nitrogen sorption analysis indicates por...

in daily life, complexity results from countless factors. culture, environment, social and economic status and physical ability all contribute, and all complicate managing ill health. pharmacists bear witness to many of these complexities and increasingly must care for what have come to be known as ‘complex patients’.  the issue of  ‘complex patients’ is one that has been addressed by healthcar...

The assignments structures of the four 1:1 pipemidic acid (pipH)–magnesium(II), calcium(II), zinc(II), and iron(III) complexes, [Mg(pip)(H2O)3(Cl)].6H2O, [Ca(pip)(H2O)3(Cl)].2H2O, [Zn(pip)(H2O)3(Cl)].4H2O, [Fe(pip)(H2O)2(Cl)2].6H2O, (where pip = deprotonated pipemidic), were synthesized through chemical reactions MgCl2.6H2O, CaCl2.2H2O, ZnCl2, FeCl3.6H2O metal salt chlorides with pipH chemother...