nowadays, increased attention has been focused on internal combustion engine fuels. regarding environmental effects of internal combustion engines particularly as sources of pollution and depletion of fossil fuels, compressed natural gas has been introduced as an alternative to gasoline and diesel fuels in many applications. a high research octane number which allows combustion at higher compre...

Rapeseed oil methyl ester (RME) and (bio)ethylene are converted into biofuel with an evenly rising boiling point curve, which fulfills the strict boiling specifications prescribed by the fuel standard EN 590 for modern (petro)diesel engines. Catalyzed by a Pd/Ru system, RME undergoes isomerizing metathesis in a stream of ethylene gas, leading to a defined olefin, monoester, and diester blend. T...

A new product (Application 460B-00) from Agilent Technologies/WassonECE uses a 5973N GC/MSD (gas chromatograph/mass selective detector) for the determination of trace levels of impurities that are moderate-to-low carbon-content such as oxygenates, mercaptans, sulfides, arsine, and phosphine in ethylene and propylene. This work describes the performance of Application 460B-00 with respect to lin...

CH4, C2H6 and C2H4 are the most important outlet gaseous of oxidative couple methane (OCM) reaction and this process is a new technology for conversion of natural gas to ethane and ethylene products. In this study, adsorption of OCM outlet hydrocarbons over 10X zeolite has been examined at equilibrium conditions. Temperature and pressure are the most effective operational parameters in the batc...

We report measurements of third-order nonlinear electric polarizabilities (hyperpolarizabilities) for ethylene, 1,3-butadiene, 1,3, 5-hexatriene and benzene molecules in the gas phase using dc electric-field induced optical second-harmonic generation. 1,2 The hyperpolarizabilities of conjugated molecules have been of interest for some time. 3-6 Because of the delocalized 7T electrons these hype...

Ethylene is unique among all plant hormones in that it is an odorless and colorless gas, and yet like other hormones it has profound effect on many aspects of plant growth and development as well as the interaction of plants with their environment. The perception and signaling of ethylene in plants has intrigued many biologists since its discovery. The gaseous ethylene was established as a grow...

Red pine (Pinus resinosa Ait.) and paper birch (Betulapapyrafera Marsh.) seedlings exposed to sulfur dioxide produced acetaldehyde and ethanol, and exhibited increased production of ethylene and ethane. Gas chromatographic measurement of head space gas from incubation tubes containing leaves or seedlings was a simple method of simultaneously measuring all four compounds. Increased ethylene prod...

Gas-phase methyl radicals have been long proposed as the key intermediate in catalytic oxidative coupling of methane, but the direct experimental evidence still lacks. Here, employing synchrotron VUV photoionization mass spectroscopy, we have directly observed the formation of gas-phase methyl radicals during oxidative coupling of methane catalyzed by Li/MgO catalysts. The concentration of gas-...