The cover picture displays fluoroalkyl radicals as reactive intermediates in the electrochemical (per)fluoroalkylation and representative examples of electrochemically fluoroalkylated small molecules. installation moieties into drug candidates significantly promotes their potency. Electrosynthesis is a sustainable powerful technology to tackle this challenging synthetic task. Consequently, fluo...

Acetic acid is an important chemical feedstock. The electrocatalytic synthesis of acetic from CO2 offers a low-carbon alternative to traditional synthetic routes, but the direct reduction comes with crossover energy penalty. CO electroreduction bypasses this, which motivates interest in cascade approach followed by acid. Here we report catalyst design strategy off-target intermediates (such as ...

Heterobimetallic polymers: the best of both worlds? The copolymers electrosynthesized in this work can benefit from conducting polymer structure and presence two metals. Their potential application sensing ascorbic acid was also explored.