We report a first-principles study of electrical transport in a single molecular conductor consisting of a buthane-dithiol sandwiched between two Au (100) electrodes. We show that the current was increased by increasing of the external voltage biases. The projected density of states (PDOS) and transmission coefficients (T(E)) under various external voltage biases are analyzed, and it suggests t...

Nicotinamide cofactor-dependent oxidoreductases have become a valuable tool for the synthesis of high value chiral compounds. The feasibility biocatalytic processes involving these enzymes stands and falls with efficiency regeneration cofactors. In this study, we describe novel NADPH method based on natural thioredoxin electron delivery system. Thioredoxin 1 (Trx1) reductase (TR) from Thermus t...

Phenylarsenious acid and diethyltin, which are known to have a great affinity for dithiol groups (Aldridge & Cremer, 1955; Peters, 1946), would be expected to compete with triethyltin for the two cysteine components of the triethyltin-binding sites. This was observed, although the affinities obtained with phenylarsenious acid and diethyltin for untreated cat haemoglobin (2x 1 0 4 ~ ' and approx...