SUPERCRITICAL CARBON DIOXIDE PROCESSING OF NANO CLAYS ANDPOLYMER/CLAY NANOCOMPOSITESbyMIHAI MANITIUAugust 2010Advisor: Rangaramanujam KannanCo-Advisor: Esin GulariMajor: Chemical EngineeringDegree: Doctor of Philosophy Effective dispersion of the fillers in a polymer matrix and improvement of polymer clayinteractions are two key challenges in the field of...

-Clay-modified electrode research indicates that adsorbed complexes are electroactive if the adsorption sites are clay edges. Interlayer adsorbed complexes may be electroactive ifa charge shuttle is added or if interlayer swelling is large. Conductivity of the film towards anionic species depends upon the swelling of the clay, which depends on the electrolyte concentration and speciation. The d...

Preparation of a novel organically modified clay from spent oil base drilling mud (SOBM) that could serve as core-shell clay filler for polymers is herein reported. Due to the hydrophilic nature of clay, its compatibility with polymer matrix was made possible through modification of the surface of the core clay sample with 3-aminopropyltriethoxysilane (3-APTES) compound prior to its use. Fourie...

The segmental dynamics of rigid, intermediate, and mobile molecular components in carboxyl terminated polybutadiene (CTPB)/ organo−clay (C18−clay) systems was characterized by fully refocused H NMR FID. In addition, H DQ NMR experiments allowed semiquantitative monitoring of changes in segmental dynamics near the interface. Both methods suggest a critical concentration of 60 wt % CTPB, indicati...

Predicting soil phosphorus (P) needs and P fertilizer requirements is important for plant nutrition and reducing environmental risk. The P requirement (PR) can be calculated from three components: the current status of soil P (P0), soil P buffer coefficient (PBC), and the soil P critical level (PCL). The PBC and PCL can be predicted from soil clay content using linear-plateau models. The PR, PB...

ABSTRACT Consolidation tests give important insights into soil compactibility. However, it requires equipment that is not always available. The costal tablelands in Northeastern Brazil have extensive areas of cohesive soils where compaction an expressive problem. This region a prominent producer food and fibers with cassava as one the leading products. Part used for flour production, generating...

Introduction: Oro-dispersible tablets are rapidly dissolved in saliva without the need for water and beneficial renal impaired, bedridden psychiatric patients. Objective: The study aimed to formulate oro-dispersible of indomethacin with reduced adverse effects, better patient compliance, faster action, convenience Methods: were prepared using three different super disintegrants; crospovidone, c...

ABS~CT Particle-size analyses of brickearth and Clay-with-flints from Kent, England, are presented. A calcareous sample of brickearth is comparable to loess. In th~ clay fraction, there is more illite (or glauconite) than kaolin; and there is some chlorite. The clay fraction of the Clay-withflints consists of smectite, illite and quartz and is probably derived directly from the Chalk. Black san...

Clay, as a rock term, describes a soft, loose, earthy material containing particles with an average grain size of less than than 0.004 mm (4 mm) in the Wentworth grain size scale and less than 0.002 mm (2 mm) in most soil investigations. Clay is composed mostly of clay minerals, but may also contain quartz, feldspar, carbonates, ferruginous material, and other non-clay materials. All clays, apa...

Iron-bearing phyllosilicates strongly influence the redox state and mobility of uranium because of their limited hydraulic conductivity, high specific surface area, and redox reactivity. Standard extraction procedures cannot be accurately applied for the determination of clay-Fe(II/III) and U(IV/VI) in clay mineral-U suspensions such that advanced spectroscopic techniques are required. Instead,...