Glycidate (2,3-epoxypropionate) stimulated CO(2) fixation in isolated spinach chloroplasts up to 100%. In the presence of glycidate the initial lag phase was abolished and the chloroplasts exported mainly 3-phosphoglycerate instead of dihydroxyacetone phosphate.Glycolate formation was not inhibited by glycidate, which is in agreement with the observation that preactivated ribulose-1,5-bisphosph...

The enzymic synthesis of the 1-phosphonomethyl isostere of fructose 1,6-diphosphate in which the 1-phosphate (-OPO(3)H(2)) is replaced by the phosphonomethyl group (-CH(2)PO(3)H(2)) is described. The kinetic properties of this fructose diphosphate isostere and of 4-hydroxy-3-oxobutylphosphonic acid, an isostere of dihydroxyacetone phosphate, with aldolase (EC 4.1.2.13), fructose diphosphatase (...

An infant with neonatal adrenoleukodystrophy experienced extreme hypotonia and virtually continuous convulsions at four months of age and died. Light and electron microscopic examination revealed evidence of myopathy and the presence of mitochondrial inclusions. Concentrations of very long-chain fatty acids were elevated in blood and fibroblasts and the oxidation of 14C-labeled fatty acids was ...

Currently obtained from glycerol through microbial fermentation, the demand of 1,3-dihydroxyacetone (DHA) has significantly grown during the course of the last decade, driven by the consumer passion for a tan and increasing awareness of UV photodamage to the skin caused by prolonged exposure to the sun. We provide an updated bioeconomy perspective into a valued bioproduct (DHA), whose supply an...

Dihydroxyacetone and lawsone, in a vanishing cream base, applied to the skin was found to protect patients with erythropoietic protoporphyria against sunlight. The use of the same ingredients in a 50% isopropyl alcohol/water solution did not induce adequate light protection. The chemically induced ultraviolet light filter in the stratum corneum allowed these patients to change their lives from ...

In the present work, we studied catalytic performance (activity and selectivity) of Pt supported on carbon systems modified with tin in glycerol oxidation H2O2 as oxidising agent at atmospheric pressure, 60 °C, base-free conditions. The conversion obtained monometallic catalyst was 37% remained unchanged addition Sn a ratio Sn/Pt = 0.4. two bimetallic PtSn catalysts were able to oxidise commerc...

In this study, activated carbon-supported Sn and Zn oxide catalysts were prepared from hydrolysis lignin used for the conversion of model solutions trioses, hexoses, lignocellulosic biomass hydrolysates to ethyl lactate. Both catalysts, SnO2@AC [email protected], able produce lactate in high yields. was a more active selective catalyst triose (dihydroxyacetone) conversion, providing 99% yield b...