The site occupation in the Cr-Ru and Cr-Os phases is computed as a function of temperature. Generally, in phases the larger atoms occupy the sites with larger coordinations numbers, as can be explained on the basis of atomic-size and electronic structure. However, for Cr2Ru and Cr2Os the atomic-size argument predicts that Ru and Os occupy the sites with larger coordination numbers, whereas the ...

The pollutant Cr(VI) is known to be very carcinogenic. In conditions of excess of Cr(VI), oxidation of D-galacturonic acid (Galur), the major metabolite of pectin, yields d-galactaric acid (Galar) and Cr(III). The redox reaction takes place through a multistep mechanism involving formation of intermediate Cr(II/IV) and Cr(V) species. The mechanism combines one- and two-electron pathways for the...

background: the purpose of this study is to investigate the relationship between the cognitive impairment and naa/cr and cho/cr ratios in the proton magnetic resonance spectroscopy (1hmrs), and to assess the importance of 1hmrs in the early diagnosis of cognitive impairment in patients with ischemic white matter lesions (wmls). materials and methods: a total of 45 patients (23males and 22 femal...

An efficient procedure and green route has been developed by using eco-friendly green synthesized palladium nanoparticles (Pd-NPs) as reusable heterogeneous nanocatalyst (Pd@nanocat) for the synthesis of diaryl ethers from the cross coupling reaction of the aryl halides with the phenol in the presence of dimethylsulfoxide (DMSO) as a solvent at 110 oC under natural ligand condition capped Pd-NP...

A simple and efficient method for the synthesis of quinolines and polycyclic quinolines using Li+ modified nanoporous Na+-montmorillonite is described. This new nanocatalyst proceeds via Friedlander annulation under solvent-free conditions. It describes our observations about a trend of catalytic activity of Lithium cation in nanoporous Na+-montmorillonite. In this study, several types of 1,3-d...

Graphene films were fabricated over synthesized MCM-41 nanocatalyst by chemical vapordeposition method, and the reaction was carried in atmospheric pressure at 750˚C. Acetylenegas used as a carbon precursor and the synthesis reaction took place in hydrogen atmosphere.Mesoporous MCM-41 was synthesized at room temperature, using wet chemical method. Thesynthesized metal free catalyst was characte...

the potential of citrobacter freundii, a gram negative bacteria for the remediation of hexavalentchromium (cr(vi)) and trivalent chromium (cr(iii)) from aqueous solutions was investigated. bioremediationof cr(vi) involved both biosorption and bioreduction processes, as compared to only biosorption processobserved with respect to cr(iii) bioremediation. in the case of cr(vi) bioremediation studi...

Recycling consumed commercial polymers is considered a highly important issue that chemists and engineers must take care of to develop the proper recycling techniques. The main objective this study find radical solution problems plastic waste by (water bottles) studying effect produced Degraded Polyethylene Terephthalate (DPET) on properties paints. DEPT was added in six quantities paint mixtur...

Chemoselective hydrogenation of unsaturated aldehyde to alcohol has attracted growing interests in recent years due its widespread applications fine chemicals. However, the C=O bond was thermodynamically and kinetically unfavorable over C=C bond. Thus, obtain from is very difficult most catalytic systems. In this work, ZnAl-hydrotalcite-supported cysteine-capped Au25 nanoclusters were used as p...