The potential of carbon nanotubes (CNT) supported cobalt catalysts for Fischer-Tropsch (FT) reaction is shown. Using the wet impregnation method cobalt on carbon nanotubes catalysts were prepared with cobalt loading varying from 15 to 45 wt. %. The catalysts are characterized by different methods including: BET physisorption, X-ray diffraction, hydrogen chemisorption, and temperature-progra...

This paper has considered the possibility of using new finishing formulations to finish Crust leather, manufactured from cattle raw materials aimed shoes and leather garments.The quality indicators their elementary chemical composition have been investigated. It was found that possess a high covering capacity due presence mineral pigments in composition. X-ray fluorescent analysis proven chromi...

background: one of the methods used for joining metals together is welding, which can be carried out using different techniques such as electric spot welding. this study evaluated the effect of electric spot welding on the load defl ection rate of stainless steel and chromium-cobalt orthodontic wires. materials and methods: in this experimental-laboratory study, load defl ection rate of 0.016 ×...

The transformation of enynes under cobalt-catalysis leads to symmetrical benzannulation products in dichloromethane. In tetrahydrofuran the cobalt-catalysed reactions afforded the unprecedented unsymmetrical benzannulation products in moderate to good yields and good regioselectivities. In addition, cyclotrimerisation of the alkyne subunit can be realised when electron-deficient enynes are appl...

Highly reactive tris-carbene Co(I) complexes [(TIMENaryl)Co]Cl react with organic azides to yield monomeric Co(III) imido complexes [(TIMENaryl)Co(NAr')](BPh4) (aryl = mes, xyl; Ar = -C6H4-CH3, -C6H4-OCH3). The cobalt-imido fragment in these complexes is electrophilic and, as a result, the imido group readily inserts into the cobalt-carbene bond, yielding bis-carbene imine cobalt complexes.

Abstract: the competition between the precipitation of cobalt ions and evolution of hydrogen gas on the cathode surface duringthe reduction process in a sulfate bath, investigation on the mechanism of metal precipitation is of great importance.In the present work, study on the kinetics of cobalt electrowinning and the mechanism of the involved reactions havebeen carried out. The obtained result...

Polyaniline-cobalt nanocomposites were synthesized bysalt of cobalt with ammonium persulphate as an oxidizing agent and aniline.This paper reports on hydrothermal technique using for synthesis and size control of cobalt nanoparticles in the composite bridge is aniline. Electrical conductivity of polyaniline alone in acidic environments, without and with cobalt nanoparticles measured.Increasing ...

We report expression and mutant phenotypes for a gene cluster in Sinorhizobium meliloti, designated cbtJKL, that has been shown to encode an ABC-type cobalt transport system. Transcription of cbtJKL initiated 384 nucleotides upstream from the cbtJ translation start codon, and the resulting 5' region contained a putative B(12)riboswitch. Expression of the cbtJKL genes appeared to be controlled b...

cythemia in man ansd experimenstal animals. The precise nsechansisnn by which cobalt exerts this actions has not yet beens Clarified comsspletely. Early studies itsdicated that cobalt acts directly by produciisg ass atsoxic coisditioss ins tise marrow,5 while later work suggested an indirect aisoxic effect oss the nsarrow (‘aused by the formatiots of cobalt-ansinso acid coissplexes.#{176} ‘ How...

A surprising effect of halide substituents on reduction potentials and catalytic activity of halogenated cobalt corroles has been deduced by experimental and computational methods; the proton-activating cobalt(I) and the cobalt(II) corrole that is formed in the step during which hydrogen is formed are characterized by NMR spectroscopy.