Recent experiments with single biological nanopores, as well as single-molecule fluorescence spectroscopy and pulling studies of protein and nucleic acid folding raised a number of questions that stimulated theoretical and computational investigations of barrier crossing dynamics. The present paper addresses a closely related problem focusing on trajectories of Brownian particles that escape fr...

Two oxygen carriers were tested with respect to chemical looping combustion (CLC) and gasification (CLG). Ilmenite, a natural ore composed mainly of iron–titanium oxide, LD Slag, an iron-based industrial waste, investigated at 850 900 °C in continuous operation 0.3 kW chemical-looping reactor system using synthetic biomass volatiles as fuel. CLC CLG conditions simulated the fuel by changing flo...

Narrow temperature range distillates from biologically active solvent refined coal-I and -II heavy-end coal liquids were fractionated according to chemical class and assayed for initiation of skin carcinogenesis in CD-1 mice. In addition, instrumental chemical analyses were performed on the distillates and their chemical fractions. Results showed that initiation activity in these complex fuel m...

DNA looping mediated by the Lac repressor is an archetypal test case for modeling protein and DNA flexibility. Understanding looping is fundamental to quantitative descriptions of gene expression. Systematic analysis of LacI•DNA looping was carried out using a landscape of DNA constructs with lac operators bracketing an A-tract bend, produced by varying helical phasings between operators and th...

Biomass and coal gasification is a rapidly developing technology due to the increasing global demand for fossil fuel resources. Gasification is the process of conversion of solid carbonaceous feedstock to a gas mixture containing CO and H2 in the presence of steam or carbon dioxide. Past research on coal gasification has shown that the process requires high temperatures (> 800 oC) and produces ...

The Chemical Looping with Oxygen Uncoupling (CLOU) process is a derivative technology of the Combustion (CLC) for combustion both renewable and non-renewable solid fuels. present work studies CO2 capture efficiency burning coal or biomass using single Cu-based oxygen carrier magnetic properties as an carrier. two different coals three biomasses was performed in 1.5 kWth CLOU continuously operat...

Although DNA looping between the initiator binding sites (iterons) of the replication origin (ori) of a plasmid and the iterons located in a cis-acting control sequence called inc has been postulated to promote negative control of plasmid DNA replication, not only was definitive evidence for such looping lacking, but also the detailed molecular mechanism of this control had not been elucidated....

Fe3O4 nanoparticles were prepared by a simple solid-state method under ambient conditions. The obtained nanoparticles, with small size and large surface area, were used as a catalyst for direct coal liquefaction (DCL). The results display that high conversion and oil yield were achieved with the nanocatalysts in direct liquefaction of two kinds of coals, i.e., Heishan coal and Dahuangshan coal....

Capture of carbon dioxide from fossil fuel power plants via adsorption and sequestration of carbon dioxide in unmineable coal seams are achievable near-term methods of reducing atmospheric emissions of this greenhouse gas. To investigate the influence of surface heterogeneity upon predicted adsorption behavior in activated carbons and coal, isotherms were generated via grand canonical Monte Car...

Generation of electricity from coal has increased over the years in the United States and around the world. Burning of coal results in annual production of upwards of 100 millions tons (United States only) of coal combustion products (CCPs). Only about a third of these products are being used to create new products while the remainder goes to landfills. Application of CCPs mixed with composted ...