Perovskite oxides with poor conductivity call for three-dimensional (3D) conductive scaffolds to demonstrate their superb reactivities for oxygen evolution reaction (OER). However, perovskite formation usually requires high-temperature annealing at 600° to 900°C in air, under which most of the used conductive frameworks (for example, carbon and metal current collectors) are reductive and cannot...

The uptake and effects (survival, weight) of copper (Cu) on Florida apple snails (Pomacea paludosa) via exposures to copper-enriched agricultural soil-water and water-only treatments were investigated. Soils were collected from citrus sites in south Florida and flooded with laboratory freshwater for 14d. Neonate apple snails (96-h-old) were then exposed to either Cu from a soil-overlying water ...

The effect of paper mill effluent on the physico-chemical properties of soils was studied under natural environment in pots experiment. The soil was treated to six rates of effluent viz. 5, 10 25, 50, 75 and 100 ml/Kg soil. The physico-chemical properties of the soil were determined before and at the end of the experiment, 12 weeks after irrigation with the effluent. Results revealed that among...

[1] Stable oxygen isotope fractionation factors (a’s) between individual dissolved carbonate species (CO2(aq.), H2CO3, HCO3 , CO3 2 ) and water, and their sum (S = [CO2(aq.)] + [H2CO3] + [HCO3 ] + [CO3 2 ]) and water are fundamental geochemical parameters. While values of a(CO2(aq.) H2O), a(HCO3 H2O), and a(CO32 H2O) have recently been examined, an overall mass balance for stable oxygen isotope...

The HSQC NMR spectrum of 15N-cisplatin in cell growth media shows resonances corresponding to the monocarbonato complex, cis-[Pt(NH3)2(CO3)Cl](-), 4, and the dicarbonato complex, cis-[Pt(NH3)2(CO3)2](-2), 5, in addition to cisplatin itself, cis-[Pt(NH3)2Cl2], 1. The presence of Jurkat cells reduces the amount of detectable carbonato species by (2.8+/-0.7) fmol per cell and has little effect on ...

The air-free reaction of CoCl2 with 1,3,5-tri(1H-1,2,3-triazol-5-yl)benzene (H3BTTri) in N,N-dimethylformamide (DMF) and methanol leads to the formation of Co-BTTri (Co3[(Co4Cl)3(BTTri)8]2·DMF), a sodalite-type metal-organic framework. Desolvation of this material generates coordinatively unsaturated low-spin cobalt(II) centers that exhibit a strong preference for binding O2 over N2, with isost...