Various PVD (physical vapor deposition) hard coatings including nitrides and metal-doped diamond-like carbons (Me-DLC) were applied in plastic injection and die-casting molds to improve wear resistance and reduce sticking. In this study, nitrides hcp-AlN (hexagonal close-packed AlN), Cr₂N, (CrAl)₂N) and Me-DLC (Si-DLC and Cr-DLC) coatings were prepared using a closed field unbalanced magnetron ...

SUPERCRITICAL CARBON DIOXIDE PROCESSING OF NANO CLAYS ANDPOLYMER/CLAY NANOCOMPOSITESbyMIHAI MANITIUAugust 2010Advisor: Rangaramanujam KannanCo-Advisor: Esin GulariMajor: Chemical EngineeringDegree: Doctor of Philosophy Effective dispersion of the fillers in a polymer matrix and improvement of polymer clayinteractions are two key challenges in the field of...

-Clay-modified electrode research indicates that adsorbed complexes are electroactive if the adsorption sites are clay edges. Interlayer adsorbed complexes may be electroactive ifa charge shuttle is added or if interlayer swelling is large. Conductivity of the film towards anionic species depends upon the swelling of the clay, which depends on the electrolyte concentration and speciation. The d...

Preparation of a novel organically modified clay from spent oil base drilling mud (SOBM) that could serve as core-shell clay filler for polymers is herein reported. Due to the hydrophilic nature of clay, its compatibility with polymer matrix was made possible through modification of the surface of the core clay sample with 3-aminopropyltriethoxysilane (3-APTES) compound prior to its use. Fourie...

The segmental dynamics of rigid, intermediate, and mobile molecular components in carboxyl terminated polybutadiene (CTPB)/ organo−clay (C18−clay) systems was characterized by fully refocused H NMR FID. In addition, H DQ NMR experiments allowed semiquantitative monitoring of changes in segmental dynamics near the interface. Both methods suggest a critical concentration of 60 wt % CTPB, indicati...

Predicting soil phosphorus (P) needs and P fertilizer requirements is important for plant nutrition and reducing environmental risk. The P requirement (PR) can be calculated from three components: the current status of soil P (P0), soil P buffer coefficient (PBC), and the soil P critical level (PCL). The PBC and PCL can be predicted from soil clay content using linear-plateau models. The PR, PB...

ABS~CT Particle-size analyses of brickearth and Clay-with-flints from Kent, England, are presented. A calcareous sample of brickearth is comparable to loess. In th~ clay fraction, there is more illite (or glauconite) than kaolin; and there is some chlorite. The clay fraction of the Clay-withflints consists of smectite, illite and quartz and is probably derived directly from the Chalk. Black san...

Polyamideimide coatings on magnet wire offer the best performance in chemical resistance and toughness. The thermal properties of polyamideimide coatings are also outstanding when compared to the cost of polyimide resins. Recent developments in polyamideimide resins are discussed and future trends-product offerings are also reviewed. Developments include corona resistance enamels, self-lubricat...

SiNx and SiCxNy coatings were fabricated with high power impulse magnetron sputtering (HiPIMS). The coatings microstructure, growth pattern, surface morphology, composition, and bonding structure were investigated by AFM, SEM, GIXRD, TEM, EDS as well as XPS, and related to the deposition parameters target powers and substrate temperature. Crosssections of SiCxNy coatings showed either dense and...