نتایج جستجو برای: bridged dihydropyrimidinone

تعداد نتایج: 7345  

Journal: :Dalton transactions 2009
Wen-Guang Wang Hong-Yan Wang Gang Si Chen-Ho Tung Li-Zhu Wu

A set of fluorophenyl-substituted adt-bridged Fe2S2 active site models of Fe-only hydrogenase, [(micro-SCH2)2NR]Fe2(CO)6 (, R=C6F4CF3-p; , R=C6H4CF3-p) and [(micro-SCH2)2NR]Fe2(CO)5(PPh3) (, R=C6F4CF3-p; , R=C6H4CF3-p), have been synthesized and well characterized. Spectroscopic and electrochemical studies demonstrate that the aryl-substituted complexes are stable toward a strong acid HBF4/Et2O...

2015
Durga Prasad

Background and Objective: A Simple, Green and efficient procedure for the synthesis of 4-aryl-3, 4-dihydropyrimidine-2(1H)-ones/thione (Biginelli reaction) from 1, 3-dicarbonyl compound, substituted aldehydes and urea/thiourea in the presence of Sodium Dodecyl Sulphate (SDS), a novel catalyst has been introduced in this study. Materials and Methods: The structures of these compounds have been c...

2016
Durga Prasad Girija Sastry Srinivasa Rao

Background and Objective: Various biginelli compounds (dihydropyrimidinones) have been synthesized efficiently and in high yields under mild, solvent free and eco-friendly conditions in a one pot reaction of 1, 3-dicarbonyl compounds, aldehydes and urea/thiourea using Sodium Dodecyl Sulphate (SDS) as a novel catalyst under two experimental conditions. Methodology: The obtained products have bee...

2015
Franz von Nussbaum Volkhart M-J Li Swen Allerheiligen Sonja Anlauf Lars Bärfacker Martin Bechem Martina Delbeck Mary F Fitzgerald Michael Gerisch Heike Gielen-Haertwig Helmut Haning Dagmar Karthaus Dieter Lang Klemens Lustig Daniel Meibom Joachim Mittendorf Ulrich Rosentreter Martina Schäfer Stefan Schäfer Jens Schamberger Leila A Telan Adrian Tersteegen

Human neutrophil elastase (HNE) is a key protease for matrix degradation. High HNE activity is observed in inflammatory diseases. Accordingly, HNE is a potential target for the treatment of pulmonary diseases such as chronic obstructive pulmonary disease (COPD), acute lung injury (ALI), acute respiratory distress syndrome (ARDS), bronchiectasis (BE), and pulmonary hypertension (PH). HNE inhibit...

Journal: :Inorganic chemistry frontiers 2023

Diruthenium( ii , iii ) paddlewheel carboxylates combine the pharmacological properties of dimetallic center with those ascribed to μ-bridged carboxylates, thus leading novel, dual-acting anticancer metallodrugs.

2016
Yusuke Takano Kazuya Ogawa

Porphyrin-fluorene conjugates bridged by ethynylene were synthesized through Pd-catalyzed cross-coupling reaction. These molecules showed strong nonlinear absorption when measured using a nanosecond Z-scan method. The largest effective two-photon absorption cross-section was observed for trisporphyrin as 2.7 × 105 GM at 760 nm, which was 10 times larger than that obtained for monoporphyrin. INT...

Journal: :Journal of Materials Chemistry C 2021

Rare examples of phenoxido-bridged Fe III –Ln binuclear complexes are synthesized, and their dynamic static magnetic properties rationalized by ab initio calculations.

Journal: :Chemical communications 2012
Teng-Hao Chen Watchareeya Kaveevivitchai Nghia Bui Ognjen Š Miljanić

Mild solvothermal dehydration of 1,1'-ferrocenediboronic acid produces a triply ferrocene-bridged boroxine cyclophane. Its crystal structure reveals a rigid trigonal prism that presents a minimal boroxine-based covalent organic polyhedron (COP).

Journal: :Acta Crystallographica Section C Crystal Structure Communications 1993

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