A new catalyst comprising cerium and silver ion-exchanged ZSM-5 zeolite is reported in this paper, for the reduction of nitric oxide by methane in the presence of excess oxygen. The bi-cation exchanged Ce-Ag-ZSM-5 catalyst was very active for this reaction, while either Ce-ZSM-5 or Ag-ZSM-5 alone showed low activity. The presence of oxygen in the feed gas mixture enhanced the activity of the ca...

Zeolites find relatively few direct applications as ion exchangers and it is perhaps for this reason that the study of their ion exchange behaviour is somewhat neglected in comparison to their other properties. Nevertheless, ion exchange is an essential part of preparative procedures for the manufacture of zeolitic sorbents and catalysts, and there is now increasing recognition of the importanc...

Lewis acidity was introduced into zeolite Y (Si/Al = 30) by a facile ion-exchange of aluminum cations followed calcination. X-ray diffraction and nitrogen physisorption suggest that the zeolitic framework is retained after these treatments. With an increase in total extra-framework modified zeolites, there pronounced number acid sites, as illustrated FTIR spectroscopy adsorbed pyridine carbon m...

We present synthesis, characterization and testing results of our applied research project, which focuses on the effects of surface and skeletal modification of zeolites for significant enhancements in current hydrocarbon (HC) separations. Zeolites are commonly used by the chemical and petroleum industries as catalysts and ion-exchangers. They have high potential for separations owing to their ...

Introduction and background: Zeolite minerals are hydrated framework aluminosilicates common to altered volcanic and volcanoclastic rocks, and the soils derived from them [1]. The mineralogy, chemistry, textural context, and abundance of zeolites provides insight into chemical weathering, hydrothermal, and metamorphic processes on Earth, in a variety of climates and tectonic settings. Zeolites ...

The catalytic activity of tin-containing zeolites, such as Sn-Beta, is critically dependent on the successful incorporation of the tin metal center into the zeolite framework. However, synchrotron-based techniques or solid-state nuclear magnetic resonance (ssNMR) of samples enriched with (119)Sn isotopes are the only reliable methods to verify framework incorporation. This work demonstrates, fo...

The combination of advantages of using zeolites and gold nanoparticles were aimed to be used for the first time to improve the characteristic properties of ion selective field-effect transistor (ISFET)-based creatinine biosensors. The biosensors with covalently cross-linked creatinine deiminase using glutaraldehyde (GA) were used as a control group, and the effect of different types of zeolites...