Single-molecule magnets (SMMs) are molecules that, below a certain temperature (TB), function as individual nanoscale magnetic particles, exhibiting magnetization hysteresis loops. As such, they represent an alternative and molecular (bottom-up) route to nanomagnetism, complementing the top-down approach to traditional magnetic nanomaterials. SMMs also exhibit fascinating quantum behavior such ...

The gliding movements of certain Cyanophyceae, Thiobacteriales, and gregarines provide relatively uncomplicated types of comparable activities suitable for quantitative observation. In spite of much discussion, little is known as to the mechanism of this sort of progression. Interpretations have been advanced by a number of writers, t but data required for formulation of a theory of this sort o...

The fundamental differences between the leading-order jump conditions, often assumed at a flame sheet in combustion theory, and the actual effect of a chemical reaction that satisfies Arrhenius kinetics with a finite activation temperature, need to be understood. These differences are “higher order” in terms of a large activation temperature analysis. However, they do provide a quantitative est...

Please cite this article in press as: R. Sivaramak The thermal dissociation of dimethyl ether has been studied with a combination of reflected shock tube experiments and ab initio dynamics simulations coupled with transition state theory based master equation calculations. The experiments use the extraordinary sensitivity provided by H-atom ARAS detection with an unreversed light source to meas...

We study hydrogen-bond dynamics in liquid water at low temperatures using molecular dynamics simulations. We analyze the dynamics using energetic and geometric definitions of a hydrogen bond, and employ two analysis methods: (i) a history-dependent correlation function, related to the distribution of bond lifetimes, and (ii) a history-independent correlation function. For method (i) we find an ...

The present understanding of wear-out and breakdown in ultrathin ( 5 0 nm) SiO2 gate dielectric films and issues relating to reliability projection are reviewed in this article. Recent evidence supporting a voltage-driven model for defect generation and breakdown, where energetic tunneling electrons induce defect generation and breakdown will be discussed. The concept of a critical number of de...

We study the problem of a Brownian particle diffusing in finite dimensions in a potential given by ψ = φ 2 /2 where φ is Gaussian random field. Exact results for the diffusion constant in the high temperature phase are given in one and two dimensions and it is shown to vanish in a power-law fashion at the dynamical transition temperature. Our results are confronted with numerical simulations wh...

guaiacol peroxidases (gp) are haem-containing enzymes participating in many physiological processes in plants. the expression pattern of these enzymes is organ-specific and developmentally regulated. methods: the presence of gp activity in extract samples, prepared from crocus sativus l. corms that were either dormant or rooting for 3, 6 and 10 days, was investigated. results: kinetic studies r...

Based on the microscopic mechanisms applicable to bulk metallic glasses (BMGs), such as free-volume theory and fracture of brittle solids, a constitutive equation for crack-like propagation velocity shear bands in BMGs is deduced, νSBcl=ν0a0exp(−ES/kT). Furthermore, flow model monolithic successfully established, logνSB=log(ν0a0)+logeES/(kTl)−logeES/(kT). The explains clearly fundamental deform...

We investigate the static and dynamic behaviors of a Br adlayer electrochemically deposited onto single-crystal Ag(100) using an off-lattice model of the adlayer. Unlike previous studies using a lattice-gas model, the off-lattice model allows adparticles to be located at any position within a two-dimensional approximation to the substrate. Interactions with the substrate are approximated by a c...