Two donor-acceptor [3]catenanes-composed of a tetracationic molecular square, cyclobis(paraquat-4,4'-biphenylene), as the π-electron deficient ring and either two tetrathiafulvalene (TTF) and 1,5-dioxynaphthalene (DNP) containing macrocycles or two TTF-butadiyne-containing macrocycles as the π-electron rich components-have been investigated in order to study their ability to form TTF radical di...

The kinetics of the photoreduction of four benzophenone derivatives by isopropyl alcohol was examined in acetonitrile, namely, tetra-meta-trifluoromethyl-, di-para-trifluoromethyl-, di-para-methoxy benzophenone, and, for comparison, the unsubstituted molecule itself. The basic spectroscopic (absorption and phosphorescence spectra) and photophysical (quantum yields and excited state energies) pr...

We report artifactual degradation of pharmaceutical compounds containing primary and secondary amines during peroxy radical-mediated oxidative stress carried out using azoalkane initiators. Two degradation products were detected when model drug compounds dissolved in methanol/water were heated to 40°C with radical initiators such as 2,2'-azobis(2-methylpropionitrile) (AIBN). The primary artifac...

polygonatum orientale desf. (asparagaceae) is herbaceous and perennial plant grown in northern parts of iran. the rhizomes of polygonatum, known as iranian shaghagho, is used in iranian traditional medicine as tonic, aphrodisiac, wound healing, lightening, kidney stone remedy, gynecological and internal wounds healing, anti-gout and rheumatism, and anti-diabetic. the aim of this study was to ev...

Reaction products from the ozonolysis of unsaturated lipids at gas-liquid interfaces have the potential to significantly influence the chemical and physical properties of organic aerosols in the atmosphere. In this study, the gas-phase dissociation behavior of lipid secondary ozonides is investigated using ion-trap mass spectrometry. Secondary ozonides were formed by reaction between a thin fil...

the present work is carried out to study the antioxidant potential of ethanolic extract of alstonia scholaris linn. ( apocynaceae ) using various in vitro tests including 1,1-diphenyl-2-picryl-hydrazil (dpph . ) free radical scavenging, metal ion chelating, hydrogen peroxide scavenging, superoxide anion radical scavenging, and ferric thiocyanate reducing ability.   ethanolic extract of alstonia...

Photodissociation dynamics of 1,2-dibromopropane has been investigated at 234 and 265 nm by using the velocity map ion imaging method. At both pump energies, a single Gaussian-shaped speed distribution is observed for the Br*((2)P(1/2)) fragment, whereas at least three velocity components are found to be existent for the Br((2)P(3/2)) product. The secondary C-Br bond cleavage of the bromopropyl...

Single-electron transmetalation is recognized as an enabling technology for the mild transfer of alkyl groups to transition metal catalysts in cross-coupling reactions. Hypercoordinate silicates represent a new and improved class of radical precursors because of their low oxidation potentials and the innocuous byproducts generated upon oxidation. Herein, we report the cross-coupling of secondar...

Alpha-terthienyl, a naturally occurring secondary plant metabolite is found in abundance in the roots of Tagetes species (family Asterasceae). It is activated by ultraviolet light and is toxic to a number of insect species. It generates oxygen radical species and has capacity to inhibit several enzymes like both in vivo and in vitro. Alpha-terthienyl possesses all the desirable properties of a ...