An apparatus is reported for real-time Raman monitoring of reactions performed using continuous-flow processing. Its capability is assessed by studying four reactions, all involving formation of products bearing α,β-unsaturated carbonyl moieties; synthesis of 3-acetylcoumarin, Knoevenagel and Claisen-Schmidt condensations, and a Biginelli reaction. In each case it is possible to monitor the rea...

An analytical nonadiabatic approach has been developed to study the dimerization gap and the optical absorption coefficient of the Su-Schrieffer-Heeger model where the electrons interact with dispersive quantum phonons. By investigating quantitatively the effects of quantum phonon fluctuations on the gap order and the optical responses in this system, we show that the dimerization gap is much m...

Absorption and electro-absorption (Stark effect) spectra of polycrystalline and lyophillized samples of pheophorbides and bacteriopheophorbides have been measured in order to obtain information on the consequences of intermolecular interactions on electronic structure. The results support the general hypothesis that large red shifts in the absorption spectra of photosynthetic aggregates are ass...

This paper reports on the absorption of molecular oxygen in the region of the A-band near 760 nm under atmospheric conditions relevant for satellite retrieval studies. We use pulsed laser cavity ring-down spectroscopy with a narrow bandwidth laser and use pressure scans to increase the accuracy of the measured oxygen extinction coefficients. Absolute binary absorption coefficients in minima bet...

Background For decades, FTIR spectroscopy has been the method of choice for detecting, identifying, and establishing the purity of chemical compounds based on their infrared absorption properties. The method typically employs a thermal radiation source emitting in the 2.5 to 25 μm spectral range (e.g., GlobarTM ). The light emitted by the source is split into two beams, one of them passing thro...

GaAs nanowires were heated locally under ambient air conditions by a focused laser beam which led to oxidation and formation of crystalline arsenic on the nanowire surface. Atomic force microscopy, photoluminescence and Raman spectroscopy experiments were performed on the same single GaAs nanowires in order to correlate their structural and optical properties. We show that the local changes of ...

Multi-walled carbon nanotubes (MWCNT)-doped TiO2 thin films were synthesized by the dip-coating method. The obtained products were characterized by SEM, EDX, XRD, and UV-vis absorption spectroscopy. The XRD patterns showed the presence of anatase phase. Absorption spectrum of MWCNT-doped TiO2 revealed a red shift in the optical absorption edge due to carbon doping. The photocatalytic properties...

Accurate and powerful computational methods developped by the author, based on the analytic resolution of the wave equation in the black hole background, allow to obtain the highly non trivial total absorption spectrum of the Black Hole. As well as phase shifts and cross sections (elastic and inelastic) for a wide range of energy and angular momentum, the angular distribution of absorbed and sc...

Accurate and powerful computational methods developped by the author, based on the analytic resolution of the wave equation in the black hole background, allow to obtain the highly non trivial total absorption spectrum of the Black Hole. As well as phase shifts and cross sections (elastic and inelastic) for a wide range of energy and angular momentum, the angular distribution of absorbed and sc...