نتایج جستجو برای: 18 and 24 crown ethers

تعداد نتایج: 16918122  

Journal: :Chemical communications 2012
Xuzhou Yan Peifa Wei Binyuan Xia Feihe Huang Qizhong Zhou

Pseudorotaxanes from self-assembly of two crown ether-based cryptand wheels and a 1,2-bis(pyridinium) ethane derivative axle were prepared.

2012
Yu-feng Wang

In the title compound, 2CH(6)N(3) (+)·2Br(-)·C(12)H(24)O(6), the 18-crown-6 mol-ecule lies about an inversion center, whereas the guanidinium cation and bromide anion are in general positions. The guanidinium cations link with the bromide anions and the crown ether mol-ecules via N-H⋯O and N-H⋯Br hydrogen bonds, thus forming a three-dimensional network.

Journal: :Molecules 2004
Waldo H Correa Janet L Scott

A benign and efficient synthesis of chiral macrocyclic 'aza-crown' ethers of varying ring size is reported. The synthesis involves a Schiff base condensation of ether linked dialdehydes of varying chain length and (1R,2R)-(-)-1,2-diaminocyclohexane under mild conditions to yield the macrocycles, which are subsequently reduced to yield the diamino analogues.

Journal: :Organic & biomolecular chemistry 2014
Wen Xue Ziyong Li Guoxing Liu Xiaoqiang Chen Tingting Li Sheng Hua Liu Jun Yin

The construction of novel mechanically interlocked structures has become a topic of great current interest due to the requirements of topology and their potential application in molecular machines and devices. Rotaxane and catenane as two basic topological frameworks can be used to construct the fused structures. In the current investigation, a class of novel ammonium backbones were synthesized...

Journal: :Chemical communications 2005
Ana C Fernandes Ricardo Fernandes Carlos C Romao Beatriz Royo

The high valent molybdenum-dioxo complex [MoO2Cl2] catalyzes the addition of dimethylphenylsilane to aldehydes and ketones to afford the corresponding dimethylphenylsilyl ethers in quantitative yield.

Journal: :Dalton transactions 2007
T Riis-Johannessen Lindsay P Harding John C Jeffery Ryan Moon Craig R Rice

Two multidentate ditopic ligands L1 and L2 which contain both N-donor and crown ether units have been synthesised. The potentially octadentate ligand L1 forms a trinuclear heterometallic double helicate with Cu(I) and Zn(II) ([Zn2Cu(L1)2](5+)), whereas L2 forms a tetranuclear heterometallic double helicate with the same metal ions ([Zn2Cu2(L2)2](6+)). Both species have been characterised by (1)...

Journal: :Dalton transactions 2005
Francisco Otón Alberto Tárraga Mária D Velasco Pedro Molina

A ferrocene-based heteroditopic receptor containing urea and crown ether units shows electrochemical responses to dihydrogenphosphate and fluoride anions. K+ cations can only be detected in the presence of dihydrogenphosphate.

Journal: :Molecules 2017
Taras M Sokolenko Maya I Dronkina Emmanuel Magnier Lev M Yagupolskii Yurii L Yagupolskii

The "chlorination/fluorination" technique for aliphatic trifluoromethyl ether synthesis was investigated and a range of products with various functional groups was prepared. The results were compared with oxidative desulfurization-fluorination of xanthates with the same structure.

Journal: :Molecules 2004
Zeliha Hayvali Mustafa Hayvali Hakan Dal

New crown ether Schiff base derivatives were prepared by the condensation of 4'-formylbenzo-15-crown-5 or 4'-formyl-5'-hydroxybenzo-15-crown-5 with 1,2-bis(2-aminophenoxy)ethane. The structures of these new compounds were confirmed on the basis of elemental analysis, IR, (1)H- and (13)C-NMR, UV-Vis and mass spectroscopic data.

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