To investigate the effect of the ionic liquid (IL) chain length on the surface properties and photoactivity of TiO2, a series of TiO2 microspheres have been synthesized via a solvothermal method assisted by 1-methyl-3-octadecylimidazolium chloride ([ODMIM][Cl]) and 1-methyl-3-tetradecylimidazolium chloride ([TDMIM][Cl]). All as-prepared samples were characterized by X-ray powder diffraction (XR...

Uniform and pinhole-free electron-selective TiO2 layers are of utmost importance for efficient perovskite solar cells. Here we used a scalable and low-cost dip-coating method to prepare uniform and ultrathin (5-50 nm) compact TiO2 films on fluorine-doped tin oxide (FTO) glass substrates. The thickness of the film was tuned by changing the TiCl4 precursor concentration. The formed TiO2 follows t...

One-dimensional heterogeneous nanostructures in the form of ZnO-coated TiO2 nanotubes (ZnO/TiO2 NTs) were fabricated by atomic layer deposition of an ultrathin ZnO coating on electrochemical anodization-formed TiO2 nanotubes (NTs) with the thickness of ZnO coating being precisely controlled at atomic scale, and the photoelectrochemical activity of the fabricated ZnO/TiO2 NTs and the influence o...

Titanium dioxide sTiO2, with the rutile structured was grown on s0001d oriented GaN and s0001d Al0.33Ga0.67N/GaN heterostructure field effect transistor sHFETd structures by molecular beam epitaxy. X-ray diffraction showed s100dTiO2 i s0001dGaNsAlGaNd and f001gTiO2 i k112̄0lGaNsAlGaNd with three rotational variants of the TiO2. Transmission electron microscopy of 50 nm thick TiO2 films on GaN an...

The catalysts of iron-doped Mn-Ce/TiO2 (Fe-Mn-Ce/TiO2) prepared by sol-gel method were investigated for low temperature selective catalytic reduction (SCR) of NO with NH3. It was found that the NO conversion over Fe-Mn-Ce/TiO2 was obviously improved after iron doping compared with that over Mn-Ce/TiO2. Fe-Mn-Ce/TiO2 with the molar ratio of Fe/Ti = 0.1 exhibited the highest activity. The results...

SiO2-TiO2 mixed oxides have been prepared by sol-gel technique from titanium tetraisopropoxide and tetraethylorthosilicate. The prepared materials were characterized by X-ray diffraction, FT-IR spectroscopy, scanning electron microscopy, nitrogen physisorption and UV-vis diffuse reflectance spectroscopy. The results indicate that compared to pure TiO2, the SiO2-TiO2 mixed oxides show higher the...

Localization of metabolites using multiplexed mass spectrometry imaging (MSI) provides important chemical information for biological research. In contrast to matrix-assisted laser desorption/ionization (MALDI), TiO2-assisted laser desorption/ionization (LDI) for MSI improves detection of low molecular mass metabolites (<500 Da) by reducing matrix background. However, the low UV absorption of Ti...

The preparation and photocatalysis of TiO2–ZnS/fluoropolymer fiber composites were investigated. The fluoropolymer nanofiber mats with carboxyl groups were prepared by electrospinning, and then titanium and zinc ions were introduced onto the fiber surfaces by the coordinating of carboxyl of fluoropolymer in solution. The TiO2–ZnS composites with diameters 15 nm to 1 lm were immobilized on the s...

Carcinoembryonic antigen (CEA) was used as the model, an ultrasensitive label-free photoelectrochemical immunosensor was developed using 2D TiO2 nanosheets and carboxylated graphitic carbon nitride (g-C3N4) as photoactive materials and ascorbic acid as an efficient electron donor. 2D TiO2 nanosheets was sythsized by surfactant self-assembly method and proved to have higher photoelectrochemical ...