Optimization of the continuous synthesis UiO-66 and derivatives with extremely high space time yield using a tubular reactor.

Ni50Co50-layered double hydroxide/UiO-66-NH2 metal–organic framework nanocomposite (Ni50Co50-LDH/UiO-66-NH2 NC) was synthesized through a facile ultrasonic-assisted hydrothermal method. UiO-66-NH2 MOF nanocrystals were in situ grown on the surface of ultrathin 2-dimensional functionalized Ni50Co50-LDH nanosheets. Using this method, uniform architecture obtained by uniformly distributing Ni50Co5...

High CO2 concentration in atmosphere causes serious environmental issues, and carbon capture storage technologies have attracted attention as a means to reduce the atmospheric concentration. Metal-organic frameworks (MOFs) can potentially be used for adsorption, but their poor stability microporosity limit applications. Herein, novel strategy was proposed combine cellulose aerogel hierarchicall...

Solid-state photovoltaic cells based on robust metal-organic frameworks (MOFs), MIL-125(Ti), MIL-125(Ti)-NH2, UiO-67, Ru(bpy)2-UiO-67, (bpy 2,2‘-bipyridine) as active components and spiro-MeOTAD (MeOTAD 2,2‘,7,7‘-tetrakis[N,N-di(p-methoxyphenyl)amino]-9,9′-spirobifluorene) hole transporting layer have been prepared., The response of this material increases in the presence bathochromic −NH2 grou...

The Internet uses are increasing day by day. The World Wide Web has become global system for providing information and services. The technological evolution however is not supported by adequate web testing methodologies. Usually web testing is carried out without following any well-defined procedure, it lacks suitable tool support. Model Based Testing has gained attention with popularization of...

Two different metal-organic frameworks containing 2,5-pyrazinedicarboxylate (PzDC2−) as linker molecule and hexanuclear {Hf6(μ3-O)4(μ3-OH)4} clusters were obtained under solvothermal reaction conditions at 120 °C. Formic acid the solvent leads to formation of Hf-UiO-66-PzDC ([Hf6(μ3-O)4(μ3-OH)4(OH)4(H2O)4(PzDC)4]), while in a water/formic mixture resulted crystallisation Hf-CAU-22-PzDC ([Hf6(μ3...

Metal organic frameworks (MOFs) have attracted great interest in photocatalysis, but their activity is hampered by the issue of severe carrier recombination. Here, through a carboxyl group assisted coordination route, MXene decorated with groups provides chelation sites enabling UiO-66-NH2(Zr/Ti) (UZT) to fabricate tightly connected UiO-66-NH2(Zr/Ti)/carboxyl-functionalized (UZT/CFMX) heterostr...