With the view to improve densification behaviour and mechanical properties of ZrB2-SiC ceramics, three synthesis routes were investigated for production ZrB2, prior fabrication ZrB2-20 vol. % SiC via spark plasma sintering (SPS). Two borothermal reduction routes, modified with a water-washing stage (BRW) partial solid solution Ti (BRS), utilised, alongside boro/carbothermal mechanism (BRCR) uti...