This study presents experimental results dealing with the possibility of transforming F-class fly ash into a zeolitic material. Two types of synthesis methods were used in the research: hydrothermal and low-temperature synthesis. As a result of alkaline reaction of fly ash with NaOH, all experimental cases yielded zeolitic material that are rich in a Na-X phase. The mineralogical composition (d...

The use of zeolitic material synthesized from coal fly ash for the immobilization of pollutants in contaminated soils was investigated in experimental plots in the Guadiamar Valley (SW Spain). This area was affected by a pyrite slurry spill in April 1998. Although reclamation activities were completed in a few months, residual pyrite slurry mixed with soil accounted for relatively high leachabl...

The zeolitic threshold method used in previous chapters is replaced with more rigorous geostatistical modeling. With this more sophisticated modeling approach, we examine whether using a threshold cutoff for zeolitic abundance is an appropriate upscaling method for characterizing small scale heterogeneity. Geostatistical techniques are used to develop variograms, kriging maps, and conditional s...

This mini review article, intends to provide the essential information about microemulsion technique as a reliable approach toward the synthesis of zeolitic nano crystallites. The strategy discussed here provides a unique, effective, and potentially general methodology to the preparation of uniform and high purity nano crystallites of template-free zeolitic materials including LTA, faujasite ty...

The potential of surfactant modified zeolites as adsorbents for mycotoxins and as carrier of the pharmaceutical drugs was investigated. Ochratoxin A OCHRA (mycotoxin) and diclofenac sodium DS (anti-inflamatory drug) were used as model substances. Surface of the clinoptilolite was modified with different amounts of quaternary ammonium ions (hexadecyltrimethyl ammonium HDTMA or octadecyldimethylb...

Calcium-rich zeolites control naturally occurring chemical degradation in the black soils (Vertisols and their intergrades). With the help of modern tools such as remote sensing, geographic information system, soil database, geological information, topography and other related datasets, an attempt was made to update the distribution of zeolitic soils in India. To ascertain the presence of Ca-ri...

Two different fly ash (FA) samples were tested for their ability to give synthetic zeolitic products. Polish bituminous (PB) and South African (SA) coal fly ash (FA) samples, derived from pilot-scale circulated fluidized bed (CFB) combustion facilities, have been utilized as raw materials. The two FAs underwent a hydrothermal activation with 1M NaOH solution at 90°C for 24 h. Two different FA/N...

Zeolitization of fly-ash by a direct route and a fusion method (two-step process) was studied using an orthogonal array of Taguchi experimental design. The effect of different processing conditions, such as type and concentration of the mineralizing agent, fusion and crystallizing temperatures and times and stirring speed, on the quantity of the zeolitic phase obtained, were evaluated. By means...

−− The objective of this work was to synthesize zeolitic products using rice husk ash (RHA) as silicon source. For the synthesis, two mineralizing agents: NaOH and KOH were tested. Chemical composition of the synthesized samples as well as their cation exchange capacity (CEC) were determined. The samples were also characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). ...

sepiolite deposits have been recently discovered in northeastern iran. however, there is still little information about its physicochemical and mineralogical characteristics. therefore, the collapse of the sepiolite (with sizes of < 63 μm) structure induced by temperature elevation in an electric furnace at 350, 550, and 850 °c for 4 hours was studied using x-ray diffraction (xrd) in combinatio...