It is well known that several ceramic materials develop an usual; and sometimes unique; combination of properties as a result of mixing different phases with similar expansion coefficients. Sometimes they are elastically stiff, have relatively low thermal expansion coefficients, good thermal and electrical conductivities, and are resistant to chemical attack. As this paper will show, their mech...

The aim of this project was to begin the development of a new three-dimensional materials fabrication capability, Additive Layer Manufacturing (ALM).[1, 2] This initial 6 months of support allowed us to assess the feasibility of printing high-quality ceramic layers. In particular, a process was developed for printing layers of Yttria-Stabilized Zirconia (YSZ). This required the development of s...

Energy-filtered transmission electron microscopy images are acquired during the reduction of a NiO-YSZ composite in H2 up to 600 °C. Temperature-resolved quantitative information about both chemistry and structure is extracted with nm spatial resolution from the data, paving the way for the development of detailed reduction models.

Laser machining of the nickel oxide–yttria-stabilized zirconia (NiO–YSZ) composite in Solid Oxide Fuel Cells (SOFCs) may be an effective approach to enlarge electrode–electrolyte interface and improve cell performance. However, laser energy can cause thermal damage surface during machined operation. In this work, microstructure changes collateral caused by pulsed on sintered NiO–YSZ state-of-th...

The objective of this paper is to manufacture free-standing solid oxide cells (SOCs) through the atmospheric plasma spray process (APS), without aid a metallic support nor need for post-process heating treatment. A five-layered cell was fabricated. Fused and crushed yttria-stabilized zirconia (YSZ) powder in 5–22 μm particle size range used order achieve dense electrolyte layer, yet still permi...

Tubular solid oxide fuel cells were fabricated and evaluated for their microstructure and electrochemical performance. The tubular substrate was prepared by casting NiO-Y2O3 stabilized ZrO2 (YSZ) slurry on the inner wall of a plastic mold (tube). The wall thickness and uniformity were controlled by slurry viscosity and rotation speed of the tube. The cells consisted of Ni-YSZ functional anode, ...

Solid oxide fuel cells are promising hydrogen energy devices. The goal of this research was to create ceramic layers for SOFCs based on yttria-stabilized zirconia (YSZ) and investigate their parameters. YSZ with a thickness 5.14 ?m porous NiO–YSZ substrate 7 pyrolytic graphite were obtained by electrophoretic deposition. X-ray diffraction electron microscopy used determine the composition, stru...

This work reports on in-situ macroscopic scale imaging of NiO-YSZ reduction under applied stress – a phase transition taking place in solid oxide electrochemical cells in reducing atmosphere of hydrogen/nitrogen mixture and at operation temperatures of up to 850 oC. This process is critical for the performance and lifetime of the cells. Energy resolved neutron imaging was applied to observe the...