Deracemization of racemic chiral compounds is an attractive approach in asymmetric synthesis, but its development has been hindered by energetic and kinetic challenges. Here we describe a catalytic deracemization method for secondary benzylic alcohols which are important synthetic intermediates end products many industries. Driven visible light only, this based on sequential photochemical dehyd...

nanocrystalline titanium (iv) oxide paste has been deposited on fluorine doped tin oxide glass substrate by the blade method. the deposited film was subjected to thermal treatment to obtain an electrode foe a photo-electrochemical cell. the electrode was sensitized with prophyrin dye which was a local dye extracted from carica papaya leaves. avaspec 2.1 spectrophotometer was used to obtain the ...

in the present work, the znfe2o4 nanoparticle has been successfully synthesized. the obtained sample was characterized by x-ray diffraction (xrd), emission scanning electron microscopy (fe-sem) and its optical property was examined by uv-vis spectrophotometer. fe-sem revealed that the particle size of the znfe2o4 of about 47 nm was synthesized. the photocatalytic performance under uv-vis and vi...

background: wearing spectacles is the most common approach in correcting the refractive errors worldwide. due to harmful effects of overexposure to solar ultraviolet radiations, the usage of multi-layer coatings in ophthalmic lenses has recently been increased. these lenses can reduce the reflections and hence increase the transmission of visible light; they can also decrease the transmission o...

The surface structure of mesoporous TiO(2) is reconstructed via a visible-light-driven reaction with benzyl alcohol molecules at mild, anaerobic conditions, which substantially extends its visible-light absorption and photocatalytic activities.