The experimental observations of vibrational mode- and bond-selective chemistry at the gas-surface interface indicate that energy redistribution within the reaction complex is not statistical on the timescale of reaction. Such behavior is a key prerequisite for efforts to use selective vibrational excitation to control chemistry at the technologically important gas-surface interface. This paper...

Vibrational predissociation spectra of the (CH3)2RSi Arn, (R = H and CH3, n = 1 and 2) ions are compared with harmonic calculations to structurally characterize these putative reactive intermediates. Although the vibrational photofragmentation behavior indicates that the Ar–Si bond is quite strong relative to that found in closed shell ions, formation of the Ar adducts is calculated to cause on...

Influence of microscopic inhomogeneity in binary liquid mixtures on their vibrational spectra is studied by doing calculations on a model liquid system. The concentration dependence of the noncoincidence effect (NCE), which is a feature of vibrational bands related to the intermolecular resonant coupling of vibrational modes, is analyzed. It is suggested that observation of convex behavior of t...

The vibrational relaxation of ground-state molecular oxygen (O2, XΣg −) has been observed, following stimulated Raman excitation to the first excited vibrational level (v=1). Time delayed laser-induced fluorescence probing of the ro-vibrational population distribution was used to examine the temporal relaxation behavior. In the presence of water vapor, the relaxation process is rapid, and is do...

The question of whether mesospheric OH(υ) rotational population distributions are in equilibrium with the local kinetic temperature has been debated over several decades. Despite several indications for the existence of non-equilibrium effects, the general consensus has been that emissions originating from low rotational levels are thermalized. Sky spectra simultaneously observing several vibra...

We observe electron emission when vibrationally excited NO molecules with vibrational state v, in the range of 9 < or = v < or =18, are scattered from a Cs-dosed Au surface. The quantum efficiency increases strongly with v, increasing up to 10(-2) electrons per NO (v) collision, a value several orders of magnitude larger than that observed in experiments with similar molecules in the ground vib...

Vibrational branching ratios and photoelectron asymmetry parameters for alternative vibrational modes in the photoionization of N 20 ( 7 u1 ) have been studied using accurate photoelectron continuum orbitals. Earlier dispersed ionic fluorescence measurements [E. D. Poliakoff, M. H. Ho, M.G. White, and G. E. Leroi, Chern. Phys. Lett. 130, 91 ( 1986)] revealed strong non-Franck-Condon vibrational...

analyzing the nonlinear vibration of beams is one of the important issues in structural engineering. according to this, an impressive analytical method which is called modified iteration perturbation method (mipm) is used to obtain the behavior and frequency of a cantilever beam with geometric nonlinear. this new method is combined by the mickens and iteration methods. moreover, this method don...

In this paper, homotopy perturbation and modified Lindstedt-Poincare methods are employed for nonlinear free vibrational analysis of simply supported and double-clamped beams subjected to axial loads. Mid-plane stretching effect has also been accounted in the model. Galerkin's decomposition technique is implemented to convert the dimensionless equation of the motion to nonlinear ordinary differ...