As a pulp bleaching agent, dimethyldioxirane (DMD) is effective and selective. In this study, it was employed as a delignifying agent or as an activating agent for hydrogen peroxide treatment in bleaching acetategrade pulp. Brightness, kappa number, degree of polymerization (DP), and alpha-cellulose content were evaluated to determine the optimal charges of DMD: 2.5% AO, and 4% HSO5, respective...

Three selected alkali-based organosolv pulps (alkali-sulfite-anthraquinone-methanol (ASAM), alkali-anthraquinone-methanol (organocell) and ethanol-soda) from agrofibre crop giant reed (Arundo donax L.) were bleached by an ozone-based TCF (totally chlorine- free) bleaching sequence AZE(R)QP (where A is an acidic pulp pre-treatment, Z is an ozone stage, (E(R)) is an alkaline extraction in the pre...

Rice straw was cooked with three levels of alkali content (12, 14 and 16%) in cooking liquor by soda-organosolv (ethanol, diethylene glycol, dimethyl formamide) process. The effect of alkali addition on yield, kappa number, brightness and viscosity of organosolv unbleached pulps was studied. The TCF bleachability of these organosolv pulps and kraft pulp was carried out using a simple three stag...

Two organic deposits accumulated in a Kraft pulp mill during pulping of Eucalyptus globulus wood and throughout a TCF (totally chlorine free) bleaching sequence were characterized. One deposit was collected after cooking and an oxygen delignification stage while the other was collected after bleaching with hydrogen peroxide. The deposits were Soxhlet extracted with acetone, and the extracts red...

The chemical composition of lipophilic extractives from process waters throughout a totally chlorine free (TCF) bleaching sequence after kraft pulping of eucalypt wood has been studied. These compounds are among the most problematic wood constituents for both TCF and zero liquid effluent (ZLE) processes, since they tend to accumulate in circuits resulting in the formation of the so-called pitch...

The addition of a phosphonated chelant (DTPMPA) at different points of a TCF bleaching sequence and its effect on pulp properties were studied in this work. An industrial Eucalyptus grandis kraft pulp was submitted to a counter-ion exchange (Ca or Na form) and was then bleached using DTPMPA in the washing or in the bleaching stages of two distinct sequences: OOpP and OQOpP (20 pulps). The count...

This study aimed at assessing the biobleachability of soda pulps obtained from olive tree pruning residue. The enzymatic (LMS) pretreatment was applied prior to a simple totally chlorine free (TCF) bleaching sequence, consisting of an alkaline extraction and a hydrogen peroxide stage. Additionally, the effect of adding xylanase jointly with or prior to LMS was evaluated. All of these enzymatic ...

The anatomical structure and chemical composition of the stem-wall material of giant reed is considered from the viewpoint of raw material characterization for industrial fiber production. The effect of stem morphology (nodes and internodes) on pulping results and general pulp properties is discussed. The advantages of application of modern organic solvent based (organosolv) pulping technologie...