In this work, chemical interactions between ozone and zeolite surface active sites are studied in order to propose a process for gaseous ozone removal. Synthetic ZSM-5 zeolites with three different Si/Al2 ratios and similar specific surface areas and microporous volumes were used in this study. Zeolite samples were characterised using Fourier Transform InfraRed spectroscopy (FTIR) and pyridine ...

There has been significant stratospheric ozone depletion since the late 1970s due to ozone-depleting substances (ODSs). With the implementation of the Montreal Protocol and its amendments and adjustments, stratospheric ozone is expected to recover towards its pre-1980 level in the coming decades. In this study, we examine the implications of stratospheric ozone recovery for the tropospheric che...

The binding energy and geometrical structure of all the possible dimeric systems of isothiocyanic acid (HNCS) with ozone have been investigated in the gas phase, theoretically. Six minima located on the singlet potential energy surface of the HNCS–ozone system at the MP2 level with binding energies (corrected with ZPE and BSSE) in the range 492.29–531.40 kcal/mol. All intermolecular interaction...

Scanningelectron microscopy (SEM) has been utilized  to examine  the morphology and topography alterations  in the surface of Poly(Lactic Acid)(PLA) fabrics due to UV/Ozoneirradiation. In the past decade, a growing attention in the usage of “Green Techniques” in industrial applications has been observed owing to many benefits such as low impurities and their relatively low cost to substitute th...

The surface ozone time series is analyzed for the seasonal and inter-annual variations and the trend in the following three categories (a) monthly mean (b) 8 hr monthly mean and (c) daily maximum monthly mean measured at 8 (urban/suburban) sites in Portugal for the period 2000–2010. The inter-annual variation of the monthly mean surface ozone time series showed an year to year variation with th...

Despite the need to understand the impact of changes in emissions and climate on tropospheric ozone, the attribution of tropospheric interannual ozone variability to specific processes has proven difficult. Here, we analyze the stratospheric contribution to tropospheric ozone variability and trends from 1953 to 2005 in the Northern Hemisphere (NH) mid-latitudes using four ensemble simulations o...

Reactions between ozone and terpenoids produce numerous products, some of which may form secondary organic aerosol (SOA). This work investigated the contribution to gas-phase SOA formation of ozone reactions with surface-sorbed D-limonene, which is common indoors. A model framework was developed to predict SOA mass formation because of ozone/terpenoid surface reactions, and it was used with ste...

[1] We examine the impact of assimilating ozone observations from the Tropospheric Emission Spectrometer (TES) on North American surface ozone abundances in the GEOS-Chem model in August 2006. The assimilation reduces the negative bias in the modeled free tropospheric ozone, which enhances the ozone flux into the boundary layer. Surface ozone abundances increased by as much as 9 ppb in western ...

[1] Continuous surface-layer ozone flux measurements over the polar, year-round snowpack at Summit, Greenland, resulted in deposition velocities (vd) that were smaller than most previous assumptions and model inputs. Substantial seasonal differences were seen in the ozone vd behavior. Spring, daytime ozone vd values showed low variability and were consistently 0.01 cm s . During summer, ozone f...

Surface ozone pollution has been a persistent environmental problem in the US and Europe as well as the developing countries. A key prerequisite to find effective alternatives to meeting an ozone air quality standard is to understand the importance of local anthropogenic emissions, the significance of biogenic emissions, and the contribution of long-range transport. In this study, an air qualit...