A lot of troilite reaction rim textures formed through sulfidation of FeNi alloy of kamacite and taenite with sulfur rich gas have been identified especially in C03 unequilibrated carbonaceous chondrites. Troilite formation through sulfidation of FeNi alloy of kamacite and taenite with sulfur rich gas in the solar nebula is expected from the reaction kinetics as well as from the equilibrium con...

In this research the effects of; increasing the amount of nickel and adding aluminum to create and prolong sulfidation resistance of Fe-Ni-Cr alloys have been investigated. Sulfidation tests were carried out at 1100°C in S/O bearing atmosphere. Prior to the tests, the specimens were annealed in argon at 1250°C for 8 hrs. Weight changes were measured and corroded deposits were analyzed byscannin...

A phase-field model is proposed to simulate corrosion kinetics under a dualoxidant atmosphere. It will be demonstrated that the model can be applied to simulate corrosion kinetics under oxidation, sulfidation and simultaneous oxidation/sulfidation processes. Phase-dependent diffusivities are incorporated in a natural manner and allow more realistic modeling as the diffusivities usually differ b...

Spray-drying and the nanoscale Kirkendall diffusion process are used to prepare nickel sulfide hollow nanospheres/reduced graphene oxide (rGO) composite powders with excellent Na-ion storage properties. Metallic Ni nanopowder-decorated rGO powders, formed as intermediate products, are transformed into composite powders of nickel sulfide hollow nanospheres/rGO with mixed crystal structures of Ni...

Numerous important Miocene and early Pliocene epithermal Au-Ag deposits are present in the northern Great Basin. Most deposits are spatially and temporally related to two magmatic assemblages: bimodal basaltrhyolite and western andesite. These magmatic assemblages are petrogenetic suites that reflect variations in tectonic environment of magma generation. The bimodal assemblage is a K-rich thol...

The selective reduction of sulfur dioxide with carbon monoxide to elemental sulfur was studied over ACsupported transition-metal oxide catalysts. According to the study, Fe2O3 /AC was the most active catalyst among the 4 AC-supported catalysts tested. By using Fe2O3 /AC, the best catalyst, when the feed conditions were properly optimized (CO/SO2 molar ratio = 2:1; sulfidation temperature, 400 ◦...

Surface-modified TiO2 nanofibers (NFs) with tunable visible-light photoactive catalysts were synthesised through electrospinning, followed by a sulfidation process. The utilization of sodium-based sulfidation precursors effectively led to the diffusion and integration of sulfur impurities into TiO2, modifying its band function. The optical band function of the sulfur-modified TiO2 NFs can be ea...

Biopolymers reinforced with nanoparticle (NP) additives are widely used in tribological applications. In this study, the effect of NP additives on the tribological properties of a green lubricant hydroxypropyl methylcellulose (HPMC) composite was investigated. The IF-MoS₂ NPs were prepared using the newly developed gas phase sulfidation method to form a multilayered, polyhedral structure. The n...

Sulfidation is a major transformation product for manufactured silver nanoparticles (Ag-MNPs) in the wastewater treatment process.We studied the dissolution, uptake, and toxicity of Ag-MNP and sulfidized Ag-MNPs (sAg-MNPs) to a model soil organism, Caenorhabditis elegans. Our results show that reproduction was the most sensitive endpoint tested for both Ag-MNPs and sAg-MNPs. We also demonstrate...

Hot reformate gas produced by reforming of heavy fuels, such as JP-8, must be desulfurized prior to its use in a solid oxide fuel cell (SOFC). This requires development of sorbent materials with high sulfur absorption efficiency and capacity at the SOFC operating temperature (650-800 C) to avoid heat exchanger penalties. Sorbent performance stability in cyclic operation of sulfidation and regen...