The synthesis of effective control structures for reactive distillation (RD) columns through a systematic analysis of the steady state relationship between potential manipulated variables (inputs) and potential controlled variables (outputs) is demonstrated. The industrially important double feed RD columns for MTBE and methyl acetate production are used as examples. In order to regulate produc...

The determination of distillation column configurations that consume the least total energy is studied. The novel contributions of the proposed designmethodology for finding globalminimum energy column sequences presented in this article include: (1) the definition of a total stripping line distance function for any sequence, (2) a robust energy targeting strategy that provides a continuously d...

INTRODUCTION In Japan, Pilot Plant of the HIDiC was built in 2005. It was commercial base scale and already achieved the consecutive distillation for 1000 hours. The energy consumption of the pilot HIDiC was only about 70% of that of a conventional distillation column. The HIDiC can lower reboiler and condenser load by heat exchange between rectifying section and stripping section. Therefore, i...

A distillation column with the possibility of heat exchange on every tray (a fully diabatic column) is optimized in the sense of minimizing its total entropy production. This entropy production counts the interior losses due to heat and mass flow as well as the entropy generated in the heat exchangers. It is observed that the optimal heating distribution, i.e. the heat exchange required on each...

Speciation modeling is an essential tool to estimate the chemical composition of an aqueous sample and to assess the bioavailability and potential risks associated with metal contamination. It is also an indispensable alternative for quantifying the metal speciation when analytical techniques are not available. In this study, we tested the effectiveness of two models, WinHumicV and the Non-Idea...

Electroplated rhodium foil was employed as the target for cyclotron production of palladium-103. An electrodissolution apparatus was found better than other dissolution methods in terms of personnel shielding and palladium-103 yield. The ion-exchange column chromatography method was simple and effective for the purification of palladium-103 and the final stripping agent of NH4Cl + NH3(1:1) was ...

Batch experiments to remove ammonia from food waste digestate were set up, and preliminary runs undertaken. These experiments were based on gas stripping in a heated column reactor; the effects of different temperatures (35, 55 and 70 degrees C) and gas flow rates (0.125, 0.250 and 0.375 L(biogas)L(digestate)(-1)min(-1)) were considered using biogas as the stripping gas. At 35 degrees C, an inc...

In the present work a novel inferential control strategy cascaded with a nonlinear profile position controller is employed to control the top and bottom product compositions of a simulated depropanizer column. The inferential model for estimating product compositions is developed using the wave propagation model, and the composition profile position of both rectifying and stripping section is c...

The organic volatile constituents of biological fluids contain clinically useful diagnostic information for the recognition of metabolic disorders in man. To gain access to this information, it was necessary to develop the methodology for reproducibly stripping the trace concentrations of volatiles from biological fluids (dynamic headspace, gas phase-stripping, solvent extraction, and the trans...

Stripper columns are used for sweetening crude oil, and they must hold product hydrogen sulfide content as near the set points as possible in the faces of upsets. Since product    quality cannot be measured easily and economically online, the control of product quality is often achieved by maintaining a suitable tray temperature near its set point. Tray temperature control method, however, is n...