Pharmaceutical compounds (PCs) and dissolved organic matter (DOM) are co-introduced into soils by irrigation with reclaimed wastewater. We targeted carbamazepine (CBZ) as a model compound to study the tertiary interactions between relatively polar PCs, DOM, and soil. Sorption-desorption behavior of CBZ was studied with bulk clay soil and the corresponding clay size fraction in the following sys...

Sorption of TCE to the caliche soil exhibited linear isotherm at the high TCE concentrations (Co=122-1300 mg L(-1)) but Freundlich isotherm at the low concentration range (1-122 mg L(-1)). Sorption strength of the carbonate fraction of the soil was about 100-fold lower than the sorption strength of soil organic matter (SOM) in the caliche soil, indicating weak affinity of TCE for the carbonate ...

Sorption interactions of plant cuticular matter with organic compounds are not yet fully understood. The objective of this study was to examine the competitive sorption-desorption interactions of the triazine herbicides (atrazine and ametryn) with cuticular fractions isolated from tomato fruits and leaves of Agave americana. The 13C NMR data suggest a rubber-like nature for the cutin. This biop...

moisture sorption isotherms for pistachio powder were determined by gravimetric method according to cost 90 project at temperatures of 15, 25, 35, and 40oc . maximum hysteresis level in sorption isotherms curve was observed at the range of water activity 0.2-0.7 . on the other hand hysteresis was diminished between adsorption-desorption isotherm curves when temperature reached 40oc. some mathem...

this study was carried out to obtain quantitative relationships between zn in equilibrium solution and that retained by 20 calcareous soils. soils were brought into equilibrium with varying solution concentrations of zn, and the amounts removed from solution were used to check the fit to six adsorption isotherms, namely, freundlich, langmuir, temkin, gunary, two surface langmuir and adjusted fr...

poly urea-formaldehyde was synthesized simply and rapidly from urea and formaldehyde by condensation polymerization and studied for the sorption of trace acid blue from aqueous solution. the optimum ph value for sorption of the acid blue was 4. experimental results showed that the sorption capacity of poly urea-formaldehyde for acid blue was determined. the synthetic polymer can be reused for 5...

Poly urea-formaldehyde was synthesized simply and rapidly from urea and formaldehyde by condensation polymerization and studied for the sorption of trace acid blue from aqueous solution. The optimum pH value for sorption of the acid blue was 4. Experimental results showed that the sorption capacity of poly urea-formaldehyde for acid blue was determined. The synthetic polymer can be reused for 5...

The ability to predict rates of contaminant sorption and desorption in the environment is essential in order to determine contaminant bioavailability, predict contaminant fate and transport, and assess risk. In this paper, we present a new method to determine sorption-desorption time scales from the temporal moments of batch experimental data. Here, the term time scale has a precise meaning: Ti...

Mobility of dissolved organic matter (DOM) strongly affects the export of nitrogen (N) and phosphorus (P) from soils to surface waters. To study the sorption and mobility of dissolved organic C and P (DOC, DOP) in soil, the pH-dependent sorption of DOM to samples from Ap, EB, and Bt horizons from a Danish agricultural Humic Hapludult was investigated and a kinetic model applicable in field-scal...

The fate of micropollutants throughout wastewater treatment systems is highly dependent on their sorption interactions with sludge matter. In this study, both the sorption and desorption kinetics of polycyclic aromatic hydrocarbons (PAHs) in activated sludge were shown to be very rapid in comparison to biodegradation kinetics. It was concluded that PAH transfer does not limit their biodegradati...