The selective reduction of sulfur dioxide with carbon monoxide to elemental sulfur was studied over ACsupported transition-metal oxide catalysts. According to the study, Fe2O3 /AC was the most active catalyst among the 4 AC-supported catalysts tested. By using Fe2O3 /AC, the best catalyst, when the feed conditions were properly optimized (CO/SO2 molar ratio = 2:1; sulfidation temperature, 400 ◦...

abstract date palm, phoenix dactylifera, is one of the most important horticultural crops in iran. the most soils in iran, especially those cultivated with palm, are calcareous with high ph. the high ph of soil causes reduction of nutrient elements absorption. findings of researches show that application of elemental sulfur along with tiobacillus bacteria in soil, due to sulfur oxidation, reduc...

Burning fuels with high sulfur content leads to SOx emissions, especially SO2, which various environmental and health problems. The maritime sector is responsible for 13% of the global anthropogenic emissions SO2. Thus, International Maritime Organization (IMO) has issued a protocol, known as MARPOL Annex VI, aims further limit SO2 derived from ships along NOx, particulate matter volatile organ...

The sulfur dioxide (SO2) compound is a primary environmental pollutant worldwide, whereas elemental (S) global commodity possessing variety of industrial as well commercial functions. chemical relationship between poisonous SO2 and commercially viable S has motivated this investigation using the Density Functional Theory calculation relative transition state barriers for two-step dehydro-sulfur...

Polysulfides formed through the breakdown of elemental sulfur or other sulfur compounds were found to be reduced to H(2)S by the hyperthermophilic archaebacterium Pyrococcus furiosus during growth. Metabolism of polysulfides by the organism was dissimilatory, as no incorporation of S-labeled elemental sulfur was detected. However, [S]cysteine and [S]methionine were incorporated into cellular pr...

The effects of soil minerals on chromate (CrVIO42-, noted as Cr(VI)) reduction by sulfide were investigated in the pH range of 7.67 to 9.07 under the anoxic condition. The examined minerals included montmorillonite (Swy-2), illite (IMt-2), kaolinite (KGa-2), aluminum oxide (gamma-Al2O3), titanium oxide (TiO2, P-25, primarily anatase), and silica (SiO2). Based on their effects on Cr(VI) reductio...

A proton exchange membrane PEM electrolyzer has been investigated as a viable system for the electrolysis step in the thermochemical conversion of sulfur dioxide to sulfuric acid for the large-scale production of hydrogen. Unfortunately, during operation, sulfur dioxide can diffuse from the anode to the cathode. This has several negative effects, including reduction to sulfur that could potenti...