In this paper, the structure of a new 16-membered macrocyclic Schiff base compound N,N′-(3,3′-dimethoxy-2,2′-(propane-1,3-diyldioxy)dibenzylidene)propane-1,3-diamine, C22H26N2O4 (1), derived from 1,3-propanediamine and 3,3′-dimethoxy-2,2′-(propane-1,3-diyldioxy)dibenzaldehyde has been studied by single crystal X-ray diffraction, DFT calculations at B3LYP/6-31G** and FT-IR spectroscopy. The titl...

Calcium dichloride tetra urea was prepared by the reaction of calcium chloride with urea in aqueous solution. The crystals are monoclinic, a= 7.633, b= 12.45 1, c= 8.118 ?,? = 113.17, Z = 4, space group P 2,/a. The crystal structure was determined by single crystal X-ray methods and refined to R= 0.041. The calcium atoms are coordinated to four oxygen atoms of urea and to two chloride ions....

The mercury (II) complex, Hg (Meca2en)I2 (1), containing bidentate Schiff base ligand  Meca2en = N,N′-bis[(E)-2-benzylidenepropylidene]ethane-1,2-diamine, has been synthesized and characterized by elemental analyses (CHN) and 1H-NMR spectroscopy. The crystal structure of 1 was determined using single-crystal X-ray diffraction. Structural investigation shows that 1 crystallizes in a monoclinic s...

The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydra...

a novel complex of cadmium (ii) [cdl0.5(no3)(h2o)](1), l= n,n-bis (o-hydroxyacetophenone) ethylene diamine, have been synthesized as single crystal and nano size. compound 1 in nano size was obtained under sonochemical irradiation and has been characterized by ir, 1hnmr spectroscopy, x-ray powder diffraction (xrd) and scanning electron microscopy (sem). the gray single crystal of compound 1 has...

The synthesis and single-crystal X-ray structure determination of the title compound (dinitrato) (1,4,8,11 -tetra-azaandecane) lead(II) is described. Crystals are monoclinic, P2 /ca= 10.271 (2)?,b= 13.524(4) ?,c= 11.298(6) ?,?=94.68(3),2=4,R,Rw, 0.036 and 0.041, respectively. The lead atom is eight-coordinate [Pb-N, 2.44 (2) - 2.55 (1)], [Pb-0,2.87 (1) - 3.06 (2)].

The crystal structure of the title chiral Schiff base compound (E)-3,4-dimethoxy[(1-phenylethyl)iminomethyl]bezyne (1) was determined by single-crystal X-ray diffraction data. The title compound was further characterized by elemental analyses (CHN), FT-IR, 1H-NMR and UV-Vis spectroscopic techniques. It crystallizes in the monoclinic space group P21 with unit cell parameters: a = 19.0121 (2), b...

A complex of N, N, N', N', -tetramethylated ethylenediamine, TMEDA, with CuCI is prepared. The crystal and molecular structure of this complex is characterized by a single-crystal X-ray diffraction study. The complex is found to contain [Cu (TMEDA) ] cation which is nearly tetrahedral and the [CuCI ) anion is linear which Cu lies on a center of symmetry. Crystals are monoclinic space grou...