A ternary phase-separation investigation of the ethyl silicate 40 (ES40) sol-gel process was conducted using ethanol and water as the solvent and hydrolysing agent, respectively. This oligomeric silica precursor underwent various degrees of phase separation behaviour in solution during the sol-gel reactions as a function of temperature and H2O/Si ratios. The solution composition within the immi...

Silica or various silicate aerogels can be characterized by highly porous, open cell, low density structures. The synthesis parameters influence the three-dimensional porous structures by modifying the kinetics and mechanism of hydrolysis and condensation processes. Numerous investigations have shown that the structure of porous materials can be tailored by variations in synthesis conditions (e...

The purpose of this study was to develop wet-chemistry approaches for the synthesis of ultradispersed and mesoporous metal oxide powders and powdery composites intended for usage in the production of ceramic materials with desired properties. The focus is on the development of template synthesis of mesoporous metal silicates as well as obtaining nano- and subnanopowders by a modified sol-gel te...

We report the synthesis of a tris-cyclometalated iridium complex which emits sky-blue light and its potential use in phosphorescent light-emitting devices. The hybrid meso-structured nanocomposites by sol-gel co-assembly with tetraethyl ortho-silicate and corresponding molecular interactions within mesopores were also demonstrated. Electroluminescent devices were fabricated using carbazole-base...

In the current study cerium or galliumcontaining silicate based 13-93 bioactive glass powders were prepared using sol-gel method. Cerium and gallium ions were chosen due to their well-known therapeutic actions and antimicrobial properties. Effect of cerium and gallium substitution (up to 5w%) on the in vitro bioactivity, and mechanical properties of the prepared powders and scaffolds were asses...

The present study describes for the first time the synthesis of silica nanoparticles starting from sodium silicate and oleic acid (OLA). The interactions between OLA and sodium silicate require an optimal OLA/OLANa molar ratio able to generate vesicles that can stabilize silica particles obtained by the sol-gel process of sodium silicate. The optimal molar ratio of OLA/OLANa can be ensured by a...

The silicate oligomerization reaction is key to sol-gel chemistry and zeolite synthesis. Numerous experimental and theoretical studies have been devoted to investigating the physical chemistry of silicate oligomers in the prenucleation stage of siliceous zeolite formation. Most of the previous quantum chemical computational work has used gas phase models or continuous solvent models for silica ...