Oil and natural gas from deep shale formations are transforming the United States economy and its energy outlook. Back in 2005, the US Energy Information Administration published projections of United States natural gas supply that stressed the need to develop an import infrastructure (1): by 2025, imports would account for almost one-third of United States consumption. When we compare those fo...

water soluble amphoteric graft copolymers of polysaccharide were synthesized via grafting of cationic monomer onto the sodium carboxymethylcellulose ()cmc)( and then used as a shale stabilizer in the water-based drilling fluids. accordingly, five types of cmc-graft copolymers with different ratios of acrylamide am)( and diallyldimethylammonium chloride dadmac)( were synthesized. grafting of mon...

The different types of elements that occurred together in conodont apparatuses are not recovered from the fossil record in the expected numbers. The causes of this are complex and difficult to study. Numerous complete articulated skeletons of Ozarkodina excavata (Branson and Mehl) have been recovered from the Eramosa Member at Hepworth, Ontario, and as a consequence, several of the potential bi...

Growing interest in the utilization of black shales for hydrocarbon development and environmental applications has spurred investigations of microbial functional diversity in the deep subsurface shale ecosystem. Lipid biomarker analyses including phospholipid fatty acids (PLFAs) and diglyceride fatty acids (DGFAs) represent sensitive tools for estimating biomass and characterizing the diversity...

Shale gas and oil are significant unconventional energy resources in the United States. Because of their low porosity and permeability, as well as the complex pore systems in organic rich shale formations, their petrophysical properties are not fully understood. Further, it is well known that wettability influences many aspects of reservoir characteristics, especially hydrocarbon storage and re...

On the basis of microand mesoscale investigations, a new mathematical formulation is introduced in detail to investigate multiscale gas-transport phenomena in organic-rich-shale core samples. The formulation includes dual-porosity continua, where shale permeability is associated with inorganic matrix with relatively large irregularly shaped pores and fractures, whereas molecular phenomena (diff...

Recent reports show growing reserves of unconventional gas are available and that there is an appetite from policy makers, industry, and others to better understand the GHG impact of exploiting reserves such as shale gas. There is little publicly available data comparing unconventional and conventional gas production. Existing studies rely on national inventories, but it is not generally possib...

This study was aimed to investigate the effect of mineral matter of Göynük oil shales (GOS) on pyrolysis and product evolution. Organic part was separated from mineral matter before pyrolysis in an isothermal pyrolysis reactor. In the demineralization step, carbonate, pyrite and silicates were removed from kerogen by using HCl, HNO3 and HF, respectively. Thereafter all samples were pyrolized in...

The state of the art of modeling fluid flow in shale reservoirs is dominated by dual porosity models which divide the reservoirs into matrix blocks that significantly contribute to fluid storage and fracture networks which principally control flow capacity. However, recent extensive microscopic studies reveal that there exist massive microand nanopore systems in shale matrices. Because of this,...