We present an analytical model of salt- and water-ion transport across an ion-selective interface based on an assumption of local equilibrium of the water-dissociation reaction. The model yields current-voltage characteristics and curves of water-ion current versus salt-ion current, which are in qualitative agreement with experimental results published in the literature. The analytical results ...

Pancreatic lipase requires colipase, a protein cofactor, to counteract the in vitro inhibition by bile salt. Lipase activity is inhibited by nonsteroidic detergents regardless of their charge and structure. Detergent-inhibited lipase is reactivated by colipase but in all cases activation is limited to a narrow range of detergent concentration. Complementary studies on the bile salt and detergen...

Injection of optimized chemistry water in enhanced oil recovery (EOR) has gained much interest in the past few years. Crude oil-water interfaces can have a viscoelastic character affected by the adsorption of amphiphilic molecules. The brine concentration as well as surfactants may strongly affect the fluid-fluid interfacial viscoelasticity. In this work we investigate interfacial viscoelastici...

The salt-water interface is one of the most important and common on earth, playing a prominent role in disciplines such as atmospheric science and biology. Despite the apparent simplicity of such interfaces, arguably the most fundamental question of what the nature and structure of the liquid water/salt interface is under ambient conditions remains unclear. Here we address this issue with an ab...

The regioselective synthesis of allylic hydroperoxide sulfonates by singlet oxygenation at the air-water interface has been found to depend on the concentration of the alkene sulfonate and added calcium salt. The regioselectivity is proposed to originate from an orthogonal alkene relative to the water surface for preferential methyl hydrogen abstraction by airborne singlet oxygen in an ene reac...

We consider 3D steady flow of fresh water over a salt water body in a confined aquifer of constant thickness D, with application to a pumping well in a coastal aquifer. With neglect of mixing, a sharp interface separates the two fluid bodies and an existing analytical solution, based on the Dupuit assumption, is adopted. The aim is to solve for the mixing between the fresh and salt waters for a...

Surface sensitive synchrotron-x-ray scattering studies reveal the distributions of monovalent ions next to highly charged interfaces. A lipid phosphate (dihexadecyl hydrogen phosphate) was spread as a monolayer at the air-water interface, containing CsI at various concentrations. Using anomalous reflectivity off and at the L3 Cs+ resonance, we provide spatial counterion distributions (Cs+) next...

Benchmark solutions are often used for the validation of numerical codes. In the field of stochastic hydrology, few closed form solutions for the statistical moments of the solutions are available. In the present contribution, we consider the problem of a sharp interface between salt and fresh waters in an aquifer of spatially variable permeability. We assume a layered structure, with permeabil...

A sharp interface numerical model is developed to simulate saltwater intrusion in multilayered coastal aquifer systems. The model takes into account the flow dynamics of salt water and fresh water assuming a sharp interface between the two liquids. In contrast to previous two-fluid flow models which were formulated using the hydraulic heads of fresh water and salt water as the dependent variabl...

The influence of dipping in hot salt solution on water absorption in nylon6 composites with dispersed aluminum powders was investigated. Dipping in hot salt solution (3mass%NaCl in distilled water) for 10 s at 373K increased the overweight of composite samples, whereas the addition of aluminum with dispersed powders (A1-addition) from zero to 40 vol%Al decreased the overweigh of the sample. Bas...