CeO(2)-SnO(2) solid solution has been reported to possess high oxygen storage/release property which possibly originates from local structural distortion. We have performed first-principles based density functional calculations of Ce(1-x)Sn(x)O(2) structure (x=0, 0.25, 0.5, 1) to understand its structural stability in fluorite in comparison to rutile structure of the other end-member SnO(2), an...

Titanium dioxide nanoparticles (TiO2NPs) induce lung inflammation in experimental animals. In this study, we conducted a comprehensive toxicogenomic analysis of lung responses in mice exposed to six individual TiO2NPs exhibiting different sizes (8, 20 and 300nm), crystalline structure (anatase, rutile or anatase/rutile) and surface modifications (hydrophobic or hydrophilic) to investigate wheth...

Titania films were grown on BaTiO3 (BTO) substrates by pulsed laser deposition to create (001)Anatase||(100)BTO, (100)Rutile||(111)BTO, and (110)Rutile||(110)BTO heterostructures. The photochemical reactivity was evaluated by observing the amount of silver reduced by each film under identical conditions. The thickest films (100 nm) had reactivities that varied with the phase of titania and the ...

By using one-dimensional rutile TiO(2) nanorod arrays as the structure-directing scaffold as well as the TiO(2) source to two consecutive hydrothermal reactions, densely aligned SrTiO(3) -modified rutile TiO(2) heterojunction photocatalysts are crafted for the first time. The first hydrothermal processing yielded nanostructured rutile TiO(2) with the hollow openings on the top of nanorods (i.e....

In this work the suitability of some Tibased coatings as coating for blood-contacting implants is analyzed. Layers of pure Ti, Ti nitride, Ti oxynitrides (TiN1-xOx with x = 0.25, 0.50, and 0.75) and Ti oxides were deposited from a plasma produced by cathodic arc evaporation under addition of N2 and/or O2. The oxynitrides are crystalline with the fcc structure of TiN up to x = 0.25. For x = 0.5 ...

In this article, using first-principles electronic structure calculations within the spin density functional theory, alternated magnetic and non-magnetic layers of rutile-CrO2 and rutile-SnO2 respectively, in a (CrO2)n(SnO2)n superlattice (SL) configuration, with n being the number of monolayers which are considered equal to 1, 2, ..., 10 are studied. A half-metallic behavior is observed for th...