نتایج جستجو برای: romp

تعداد نتایج: 482  

2003
Stephen Martin

It is shown that R & D joint ventures make it more likely that firms will be able to sustain tacit product-market collusion, all else equal. JEL classification: LI3; 032

2003

Ring-opening metathesis polymerization (ROMP) is one of the most widely used polymerizations. With the development of well-defined catalysts, such as (t-BuO)2(ArN)Mo=CH(t-Bu) (1), Cl2(PCy3)2Ru=CHPh (2), and Cl2(PCy3)(IMesH2)Ru=CHPh (3), more controlled polymer structures have been obtained by either living polymerization or chain transfer induced polymerization. However, these catalysts suffer ...

2009
P. Longo C. Costabile F. Grisi G. Siniscalchi P. Ciambelli M. Sarno C. Leone D. Sannino Don Melillo

The synthesis of polynorbornene by ring opening metathesis polymerization (ROMP) in the presence of 1 2 generation Grubbs catalyst-functionalized nanotubes, is reported. A characterization of the 2 generation Grubbs catalystfunctionalized nanotubes was performed by TGA (Thermogravimetric Analysis) on-line connected with a quadrupole-mass spectrometer, in order to quantify the amount of catalyst...

Journal: :Bio-medical materials and engineering 2015
Muhammad Sajjad Irfan Mehmood Sung Wook Baik

Image super-resolution (SR) plays a vital role in medical imaging that allows a more efficient and effective diagnosis process. Usually, diagnosing is difficult and inaccurate from low-resolution (LR) and noisy images. Resolution enhancement through conventional interpolation methods strongly affects the precision of consequent processing steps, such as segmentation and registration. Therefore,...

2003

Olefin metathesis polymerization, in particularly ring-opening metathesis polymerization (ROMP), has been a popular topic of modern research. Two other types are acyclic diene metathesis polymerization (ADMET) and cyclopolymerization of diynes. To date, there has been no report on a metathesis polymerization utilizing more than one metathesis process. Herein, the concept of multiple olefin meta...

Journal: :Journal of the American Chemical Society 2009
Erin M Kolonko Jason K Pontrello Shane L Mangold Laura L Kiessling

The applications of block copolymers are myriad, ranging from electronics to functionalized resins to therapeutics. The ring-opening metathesis polymerization (ROMP) is an especially valuable reaction for block copolymer assembly because each block can be generated with length control. We sought to use this polymerization to expand the repertoire of block copolymers by implementing a strategy t...

Journal: :Journal of the American Chemical Society 2009
Hua Lu Jing Wang Yao Lin Jianjun Cheng

We report here the integration of ring-opening metathesis polymerization (ROMP) and ring-opening polymerization of the amino acid N-carboxyanhydride (NCA) to allow facile synthesis of brush-like polymers containing polypeptide as the brush side chains. ROMP of N-trimethylsilyl norbornenes rendered the preparation of poly(norbornene)s bearing pendant N-TMS groups. With no need to purify the resu...

Journal: :Macromolecules 2009
Ron Walker Rosemary M Conrad Robert H Grubbs

The living ring-opening metathesis polymerization (ROMP) of trans-cyclooctene (tCO) was investigated. ROMP of tCO in the presence of PPh(3) in THF leads to the formation of narrowly dispersed polycyclooctene (PCO). The presence of PPh(3) as an additive and the use of THF as a solvent were demonstrated to be necessary to suppress competing secondary metathesis processes in the ROMP of tCO. Under...

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