ZnO and ZnO:Mn nanocrystals synthesized via reverse micelle method. The size, band gap, Urbach energy, optical constants and penetration depth of nanocrystals were calculated by UV-vis spectroscopy data. The surface morphology was studied with the use of scanning electron microscope (SEM). Moreover the samples exposed to Gama ray source of 60Co and their thermoluminescence properties...

zno and zno: mn nanocrystals synthesized via reverse micelle method. the structural properties nanocrystals were investigated by xrd and transmission electron microscopy (tem). the xrd results indicate that the synthesized nanocrystals had a pure wurtzite (hexagonal phase) structure. the various optical properties of these nanocrystals such as optical band gap energy, refractive index, dielectr...

The addition of sterically stabilized colloidal particles to a phase-separating microemulsion leads to dramatic changes in its demixing behavior, especially during the later stages. Our microemulsion is composed of reverse micelles of sodium dodecyl sulfate, pentanol, and water in a dodecane continuous phase which separates into micelle-rich and micelle-poor phases above a lower critical soluti...

The water core of reverse micelles has been extensively used as the site for synthesis of a variety of materials. However, water-in-oil reverse micelles have a limited range of temperatures over which they are stable as a single phase. Directing heat to the water cores, the usual site of synthesis without heating the bulk provides added opportunities for synthesis. Microwave radiation is a meth...

A reverse micelle based approach is reported for the synthesis of BaCO3 nanowires with lengths up to 100 μm and diameters as small as 10-30 nm, each of which is a continuous single crystal with the c-axis along the wire length axis. The synthesis is achieved by the reaction of barium and carbonate ions solubilized in the polar cores of nonionic reverse micelles of C12E4 (tetraethylene glycol mo...

A significant fraction of the proteins encoded by the human and other genomes appears to be significantly unfolded in vitro. This will undoubtedly hamper attempts to characterize their structure by classical crystallographic or solution NMR methods. Here we show that encapsulation of a metastable protein within the restricted volume a reverse micelle can be used to force fold the protein and al...

The enzyme hydrogenase isolated from the sulphate reducing anaerobic bacterium Desulfovibrio gigas was encapsulated in reverse micelles of AOT–water–isooctane. The enzyme ability to consume molecular hydrogen was studied as a function of the micelle size (given by Wo = [H2O]/[organic solvent]). A peak of catalytic activity was obtained for Wo = 18, a micelle size theoretically fitting the heter...