a poly(vinyl chloride) membrane based on a new a-dioxime derivative as membrane carrier was prepared andinvestigated as a cr(iii) selective electrode. the electrode exhibits a good potentiometric response for cr(iii)over a wide concentration range 1.0 x 10-6 to 1.0 x 10-1 m with a slope 19.5+0.5 mv/decade and low detectionlimit of 8.9 x 10-7 m. it has a fast response time < 15 s. the best perfo...

a pvc membrane cr(iii) ion selective electrode has been constructed using 2h-1,4-benzothioazine-2,3(4h)dione dioxime (btd) as membrane carrier. the influence of membrane composition on the electroderesponse was studied. the electrode exhibits a nernstian response over a cr(iii) concentration range of 1.0 x10 6 to 1.0>< 10-1 m (r = 0.99) with a slope of 19.5 ± 0.5 mv per decade of concentration,...

a novel potentiometric ion-selective pvc membrane sensor for analysis of atorvastatin (at) in pharmaceutical preparations based on atorvastatin-(tetraphenyl borate), (at-(tpb)2) as sensing element, tetraphenyl borate as additive and tris-2-ethyl-hexyl phosphate (top) as plasticizer solvent was prepared. the electrode shows a good nernestian response over the concentration range of 0.09–5586 µg ...

a highly selective electrode for bromide ion based on aza pyrilium derivative as an excellentionophore is described.the sensor exhibits a good linear response with a slope of ( 60±1 ) mv per decadeover the concentration range of ( 1×10-3 – 9×10-6 m ) , and a detection limit of ( 3×10-6 m ) of bromideions .the electrode response is independent of ph in the range of(4.0 –9.5).selectivity coeffici...

A PVC membrane Ni(II) ion selective electrode has been constructed using (1E,2E)-bis(2-aminophenyl)N'1,N'2-dihydroxyethanebis as membrane carrier. The electrode exhibited a goodpotentiometric response for Ni(II) over a wide concentration range 1.0×10-4 to 1.0×10-1M with aslope of 29.4±0.5 mV/decade a and a working pH range of 6.5-9.0. It had a fast response time of≤20s. The best performance was...

In the present paper, the potentiometric response characteristics of a metalloporphyrin-based electrode in o-nitrophenyloctylether (o-NPOE) plasticized polyvinyl chloride (PVC) membrane are presented for a set of monovalent anions. As membrane ionophore, 5,10,15,20-tetrakis-(4-methoxyphenyl)-porphyrin-Co(II) (CoTMeOPP) was used. To establish the optimum composition of the membrane, different mo...

In this research, a PVC membrane electrode for Manganese (II) ions based on N-(2-Picolinamidoethyl)Picolinamide as neutral carrier was prepared. The electrode exhibits a Nemstian responseover Mn(II) concentration range of (1.0 x10-5 t01.0 X 10-1M) with a slope of 29.3±0.5 mV perdecade of concentration with a working pH range of 4.0-9.0. It has a fast response time (

a pvc membrane ni(ii) ion selective electrode has been constructed using (1e,2e)-bis(2-aminophenyl)n'1,n'2-dihydroxyethanebis as membrane carrier. the electrode exhibited a goodpotentiometric response for ni(ii) over a wide concentration range 1.0×10-4 to 1.0×10-1m with aslope of 29.4±0.5 mv/decade a and a working ph range of 6.5-9.0. it had a fast response time of≤20s. the best performance was...

a pvc membrane ni(ii) ion selective electrode has been constructed using (1e,2e)-bis(2-aminophenyl)n&apos;1,n&apos;2-dihydroxyethanebis as membrane carrier. the electrode exhibited a goodpotentiometric response for ni(ii) over a wide concentration range 1.0×10-4 to 1.0×10-1m with aslope of 29.4±0.5 mv/decade a and a working ph range of 6.5-9.0. it had a fast response time of≤20s. the best perfo...