The dependence on ionic strength of protonation of glycine and its complexation with dioxouranium (VI) is reported in sodium perchlorate and sodium chloride solutions as background salts. The measurements have been performed at 25±0.1°C and various ionic strengths in the range 0.1 to 1.0 mol , using a combination of potentiometric and spectrophotometric techniques. The overall analysis  of the ...

In this research, the protonation constant value of tannic acid was determined at 25 °C and different ionic strengths (0.1 to 0.7 mol/dm3 NaCl) using potentiometric titration technique. The dependence of protonation constant on ionic strength was modeled and discussed by a Debye-Hückel type equation. Then, based on the obtained data from experiments, the minimizing Sum o...

the dependence on ionic strength of protonation of glycine and its complexation with dioxouranium (vi) is reported in sodium perchlorate and sodium chloride solutions as background salts. the measurements have been performed at 25±0.1°c and various ionic strengths in the range 0.1 to 1.0 mol , using a combination of potentiometric and spectrophotometric techniques. the overall analysis  of the ...

Equilibrium constants of Cadmium Oxide (CdO) nanoparticles complexes in human cancer cells with DNA/RNA ligands have been studied with biospectroscopic methods such as 1HNMR, 13CNMR, 31PNMR, Attenuated Total Reflectance Fourier Transform Infrared (ATR–FTIR) and FT–Raman spectroscopies in cosolvent systems at 10, 20, 30°C ± 0.5 and 1 mol.dm–3 ionic strength, was maintained using Sodium Chloride ...

The formation constants of the species formed in the systems H+ + Mo(VI) + histidine and H+ +histidine have been determined at different aqueous solutions of methanol (0 - 45 % v/v) at 25 °C andconstant ionic strength (0.1 mol dm-3 sodium perchlorate), using a combination of spectrophotometricand potentiometric techniques. The composition of the complex species was determined by thecontinuous v...

The sulfonated tripodal polyaza-polycatechol-amine ligand tris(2,3-hydroxy-5-sulfobenzylamine) ethyl)amine (STRENCAT) was synthesized and its protonation constants determined by potentiometry at 25 degrees C and in 0.1 mol dm(-3) NaClO(4). In the adopted experimental conditions (2.5 < p[H(+)] < 11.5), six of the virtual thirteen protonation constants of STRENCAT were determined. The deprotonati...

the acid-base equilibria of glycine have been studied in different aqueous solutions of 1,4-dioxane(0-50 % by v/v) using potentiometric method. in this study, the macro and micro protonationconstants of the amino acid and its tautomeric constant have been determined at 25 °c and constantionic strength 0.1 mol dm-3 (nacl). the protonation and the tautomeric constants of glycine indifferent binar...

Simulation of chemical element adsorption, release, and transport is possible without the need to perform time consuming, detailed adsorption studies on multiple samples by incorporating prediction equations into chemical speciation–transport models before simulating. Adsorption models also assume that the chemical species in a mixture is at chemical equilibrium which is the state in which the ...

The acid-base equilibria of glycine have been studied in different aqueous solutions of 1,4-dioxane(0-50 % by v/v) using potentiometric method. In this study, the macro and micro protonationconstants of the amino acid and its tautomeric constant have been determined at 25 °C and constantionic strength 0.1 mol dm-3 (NaCl). The protonation and the tautomeric constants of glycine indifferent binar...

The complexation reactions between Cu2+, Pd2+ and Ni2+ metal ions with promethazine (PM) in water or DMF were studied by the spectrophotometric methods at [(15, 25,35 and 45±0.1) °C]. The complexation process was optimized in terms of pH, temperature and contact time. The stoichiometry of the complex was found to be 1:1 (metal ion/ligand). The formation constants of the resulting complexes were...