Catalytic dynamic kinetic resolution (DKR) of racemic azlactones with EtOD using squaramide-based dimeric cinchona alkaloid organocatalysts is shown to be a highly effective strategy for the preparation of enantiomerically pure α-deuterated chiral α-amino acids.

Objective The aim of this study was to evaluate the non-genomic action of thyroxin on sperm kinetic and its probable use to improve sperm recovery after applying an enrichment method like “swim-up” in comparison with the available one, pentoxifylline. MaterialsAndMethods This is an experimental study. A total of 50 patients were recruited, followed by infertility consultation. Conventional sper...

We report on the development of a test-particle based kinetic Monte Carlo code for large systems and its application to simulate matter in the continuum regime. Our code combines advantages of the Direct Simulation Monte Carlo and the Point-of-Closest-Approach methods to solve the collision integral of the Boltzmann equation. With that, we achieve a high spatial accuracy in simulations while ma...

Like any other precipitation process, in supercritical water hydrothermal synthesis (SWHS), the need to improve product quality and minimize production cost requires understanding and optimization of Particle Size Distribution (PSD). In this work, using Population Balance Equation (PBE) containing nucleation and growth terms, the reactive precipitation of zirconia nanoparticles prepared by ...

background and aims: from the past studies, it has been proved that consumption of heavy metals by humans may cause several chronicle problems like cancer, kidney and liver damage, high blood pressure and low blood pressure problems and etc. so, it has become very crucial to remove these heavy metals from industrial wastewater. the aim of this study was to find out a low cost and easy available...

Adenylate deaminase (EC 3.5.4.6) may help to regulate the adenine nucleotide catabolism characteristic of such disease states as myocardial ischaemia. We report analysis of the molecular, kinetic and allosteric properties of rabbit heart adenylate deaminase when extracted and purified under phosphate-free conditions (i.e., with Hepes/KOH). The enzyme's subunit molecular mass (approximately 81 k...

A potentially general kinetic method for the investigation of active-site availability in preparations of macromolecular catalysts was developed. Three kinetic models were considered: (a) the conventional two-step model of enzyme catalysis, where the preparation contains only active catalyst (E(a)) and inert (i.e. non-binding, non-catalytic) material (E(i)); (b) an extension of the conventional...

This review encompasses the fundamental aspects of electrophoretic deposition technique, factors influencing the deposition process, kinetic aspects, types of EPD, the driving forces, preparation of electrophoretic suspension, stability and control of suspension, mechanisms involved in EPD, multicomponent/composite deposition, drying of deposits obtained by EPD. Numerous applications including ...